1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene

There are three independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)Br(3)O(3), two of which have approximate trigonal symmetry, the third being conformationally different as it adopts near mirror symmetry. The crystal structure features C—H⋯Br inter­actions, a weak C—H⋯O h...

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Detalles Bibliográficos
Autores principales: Koch, Niklas, Seichter, Wilhelm, Mazik, Monika
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647873/
https://www.ncbi.nlm.nih.gov/pubmed/23723839
http://dx.doi.org/10.1107/S1600536813008441
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author Koch, Niklas
Seichter, Wilhelm
Mazik, Monika
author_facet Koch, Niklas
Seichter, Wilhelm
Mazik, Monika
author_sort Koch, Niklas
collection PubMed
description There are three independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)Br(3)O(3), two of which have approximate trigonal symmetry, the third being conformationally different as it adopts near mirror symmetry. The crystal structure features C—H⋯Br inter­actions, a weak C—H⋯O hydrogen bond, π–π inter­actions [minimum ring centroid separation = 3.4927 (18) Å] and a short Br⋯Br contact [3.5894 (5) Å], resulting in a three-dimensional supramolecular network.
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spelling pubmed-36478732013-05-30 1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene Koch, Niklas Seichter, Wilhelm Mazik, Monika Acta Crystallogr Sect E Struct Rep Online Organic Papers There are three independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)Br(3)O(3), two of which have approximate trigonal symmetry, the third being conformationally different as it adopts near mirror symmetry. The crystal structure features C—H⋯Br inter­actions, a weak C—H⋯O hydrogen bond, π–π inter­actions [minimum ring centroid separation = 3.4927 (18) Å] and a short Br⋯Br contact [3.5894 (5) Å], resulting in a three-dimensional supramolecular network. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3647873/ /pubmed/23723839 http://dx.doi.org/10.1107/S1600536813008441 Text en © Koch et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Koch, Niklas
Seichter, Wilhelm
Mazik, Monika
1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene
title 1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene
title_full 1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene
title_fullStr 1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene
title_full_unstemmed 1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene
title_short 1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene
title_sort 1,3,5-tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647873/
https://www.ncbi.nlm.nih.gov/pubmed/23723839
http://dx.doi.org/10.1107/S1600536813008441
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AT seichterwilhelm 135trisbromomethyl246trimethoxybenzene
AT mazikmonika 135trisbromomethyl246trimethoxybenzene

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