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2,2′,2′′-[(2,4,6-Trimeth­oxy­benzene-1,3,5-tri­yl)tris­(methyl­ene)]tris­(isoindole-1,3-dione)

The title mol­ecule, C(36)H(27)N(3)O(9), adopts an almost symmetric conformation in which the mean planes of the phthalimido units are inclined at dihedral angles of 81.1 (1), 85.3 (1) and 86.3 (1)° with respect to the plane of the central aromatic ring. The O atoms are involved in intra- and inter­...

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Detalles Bibliográficos
Autores principales: Rosien, Jan-Ruven, Seichter, Wilhelm, Mazik, Monika
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647874/
https://www.ncbi.nlm.nih.gov/pubmed/23723840
http://dx.doi.org/10.1107/S1600536813008428
Descripción
Sumario:The title mol­ecule, C(36)H(27)N(3)O(9), adopts an almost symmetric conformation in which the mean planes of the phthalimido units are inclined at dihedral angles of 81.1 (1), 85.3 (1) and 86.3 (1)° with respect to the plane of the central aromatic ring. The O atoms are involved in intra- and inter­molecular C—H⋯O hydrogen bonding. The crystal structure also features π–π arene inter­actions [minimum ring centroid separation = 3.683 (2) Å]. The present mode of non-covalent interactions leads to a three-dimensional supramolecular architecture.