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4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile

In the title compound, C(19)H(14)FN(3)O(3), the central pyran ring adopts a boat conformation with the O atom and the quaternary C atom diagonally opposite displaced by 0.068 (1) and 0.075 (1) Å, respectively, above the mean plane defined by the other four ring atoms. The co-planar atoms of the pyra...

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Autores principales: Vishnupriya, R., Suresh, J., Sivakumar, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647880/
https://www.ncbi.nlm.nih.gov/pubmed/23723846
http://dx.doi.org/10.1107/S1600536813009008
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author Vishnupriya, R.
Suresh, J.
Sivakumar, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_facet Vishnupriya, R.
Suresh, J.
Sivakumar, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_sort Vishnupriya, R.
collection PubMed
description In the title compound, C(19)H(14)FN(3)O(3), the central pyran ring adopts a boat conformation with the O atom and the quaternary C atom diagonally opposite displaced by 0.068 (1) and 0.075 (1) Å, respectively, above the mean plane defined by the other four ring atoms. The co-planar atoms of the pyran ring and the fluoro­phenyl ring are nearly perpendicular, as evidenced by the dihedral angle of 87.11 (1)°. The amine group forms an intra­molecular N—H⋯O(nitro) hydrogen bond. In the crystal, mol­ecules are linked into parallel chains along [100] by weak N—H⋯N and C—H⋯N(nitro) hydrogen bonds, generating C(8) and C(9) graph-set motifs, respectively.
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spelling pubmed-36478802013-05-30 4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile Vishnupriya, R. Suresh, J. Sivakumar, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(14)FN(3)O(3), the central pyran ring adopts a boat conformation with the O atom and the quaternary C atom diagonally opposite displaced by 0.068 (1) and 0.075 (1) Å, respectively, above the mean plane defined by the other four ring atoms. The co-planar atoms of the pyran ring and the fluoro­phenyl ring are nearly perpendicular, as evidenced by the dihedral angle of 87.11 (1)°. The amine group forms an intra­molecular N—H⋯O(nitro) hydrogen bond. In the crystal, mol­ecules are linked into parallel chains along [100] by weak N—H⋯N and C—H⋯N(nitro) hydrogen bonds, generating C(8) and C(9) graph-set motifs, respectively. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3647880/ /pubmed/23723846 http://dx.doi.org/10.1107/S1600536813009008 Text en © Vishnupriya et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vishnupriya, R.
Suresh, J.
Sivakumar, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile
title 4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile
title_full 4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile
title_fullStr 4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile
title_full_unstemmed 4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile
title_short 4-(4-Fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbo­nitrile
title_sort 4-(4-fluoro­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4h-pyran-3-carbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647880/
https://www.ncbi.nlm.nih.gov/pubmed/23723846
http://dx.doi.org/10.1107/S1600536813009008
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