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N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide

In the title compound, C(24)H(20)N(6)O, the pyridin-3-yl groups on the ethyl­ene fragment are found in a trans conformation with a C(py)—C(e)—C(e)—C(py) (py = pyridine, e = ethylene) torsion angle of 179.2 (3)°. The dihedral angle between the pyridine rings is 3.5 (1)°. In the crystal, N—H⋯N and C—H...

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Autores principales: Quiroa-Montalván, Claudia M., Chávez, Daniel, Reyes-Martínez, Reyna, Morales-Morales, David, Parra-Hake, Miguel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647883/
https://www.ncbi.nlm.nih.gov/pubmed/23723849
http://dx.doi.org/10.1107/S1600536813008544
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author Quiroa-Montalván, Claudia M.
Chávez, Daniel
Reyes-Martínez, Reyna
Morales-Morales, David
Parra-Hake, Miguel
author_facet Quiroa-Montalván, Claudia M.
Chávez, Daniel
Reyes-Martínez, Reyna
Morales-Morales, David
Parra-Hake, Miguel
author_sort Quiroa-Montalván, Claudia M.
collection PubMed
description In the title compound, C(24)H(20)N(6)O, the pyridin-3-yl groups on the ethyl­ene fragment are found in a trans conformation with a C(py)—C(e)—C(e)—C(py) (py = pyridine, e = ethylene) torsion angle of 179.2 (3)°. The dihedral angle between the pyridine rings is 3.5 (1)°. In the crystal, N—H⋯N and C—H⋯O=C inter­actions form a layer arrangement parallel to the bc plane. The compound displays disorder of the ethyl­ene fragment over two positions with an occupancy ratio of 0.676 (7) to 0.324 (7) that extends into the amide section of the nicotinamide moiety.
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spelling pubmed-36478832013-05-30 N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide Quiroa-Montalván, Claudia M. Chávez, Daniel Reyes-Martínez, Reyna Morales-Morales, David Parra-Hake, Miguel Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(20)N(6)O, the pyridin-3-yl groups on the ethyl­ene fragment are found in a trans conformation with a C(py)—C(e)—C(e)—C(py) (py = pyridine, e = ethylene) torsion angle of 179.2 (3)°. The dihedral angle between the pyridine rings is 3.5 (1)°. In the crystal, N—H⋯N and C—H⋯O=C inter­actions form a layer arrangement parallel to the bc plane. The compound displays disorder of the ethyl­ene fragment over two positions with an occupancy ratio of 0.676 (7) to 0.324 (7) that extends into the amide section of the nicotinamide moiety. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3647883/ /pubmed/23723849 http://dx.doi.org/10.1107/S1600536813008544 Text en © Quiroa-Montalván et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Quiroa-Montalván, Claudia M.
Chávez, Daniel
Reyes-Martínez, Reyna
Morales-Morales, David
Parra-Hake, Miguel
N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide
title N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide
title_full N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide
title_fullStr N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide
title_full_unstemmed N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide
title_short N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide
title_sort n-{1,2-bis(pyridin-3-yl)-2-[(e)-(pyridin-3-yl)methyl­idene­amino]­eth­yl}nicotinamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647883/
https://www.ncbi.nlm.nih.gov/pubmed/23723849
http://dx.doi.org/10.1107/S1600536813008544
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