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N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide
In the title compound, C(24)H(20)N(6)O, the pyridin-3-yl groups on the ethylene fragment are found in a trans conformation with a C(py)—C(e)—C(e)—C(py) (py = pyridine, e = ethylene) torsion angle of 179.2 (3)°. The dihedral angle between the pyridine rings is 3.5 (1)°. In the crystal, N—H⋯N and C—H...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647883/ https://www.ncbi.nlm.nih.gov/pubmed/23723849 http://dx.doi.org/10.1107/S1600536813008544 |
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author | Quiroa-Montalván, Claudia M. Chávez, Daniel Reyes-Martínez, Reyna Morales-Morales, David Parra-Hake, Miguel |
author_facet | Quiroa-Montalván, Claudia M. Chávez, Daniel Reyes-Martínez, Reyna Morales-Morales, David Parra-Hake, Miguel |
author_sort | Quiroa-Montalván, Claudia M. |
collection | PubMed |
description | In the title compound, C(24)H(20)N(6)O, the pyridin-3-yl groups on the ethylene fragment are found in a trans conformation with a C(py)—C(e)—C(e)—C(py) (py = pyridine, e = ethylene) torsion angle of 179.2 (3)°. The dihedral angle between the pyridine rings is 3.5 (1)°. In the crystal, N—H⋯N and C—H⋯O=C interactions form a layer arrangement parallel to the bc plane. The compound displays disorder of the ethylene fragment over two positions with an occupancy ratio of 0.676 (7) to 0.324 (7) that extends into the amide section of the nicotinamide moiety. |
format | Online Article Text |
id | pubmed-3647883 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478832013-05-30 N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide Quiroa-Montalván, Claudia M. Chávez, Daniel Reyes-Martínez, Reyna Morales-Morales, David Parra-Hake, Miguel Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(20)N(6)O, the pyridin-3-yl groups on the ethylene fragment are found in a trans conformation with a C(py)—C(e)—C(e)—C(py) (py = pyridine, e = ethylene) torsion angle of 179.2 (3)°. The dihedral angle between the pyridine rings is 3.5 (1)°. In the crystal, N—H⋯N and C—H⋯O=C interactions form a layer arrangement parallel to the bc plane. The compound displays disorder of the ethylene fragment over two positions with an occupancy ratio of 0.676 (7) to 0.324 (7) that extends into the amide section of the nicotinamide moiety. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3647883/ /pubmed/23723849 http://dx.doi.org/10.1107/S1600536813008544 Text en © Quiroa-Montalván et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Quiroa-Montalván, Claudia M. Chávez, Daniel Reyes-Martínez, Reyna Morales-Morales, David Parra-Hake, Miguel N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide |
title |
N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide |
title_full |
N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide |
title_fullStr |
N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide |
title_full_unstemmed |
N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide |
title_short |
N-{1,2-Bis(pyridin-3-yl)-2-[(E)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide |
title_sort | n-{1,2-bis(pyridin-3-yl)-2-[(e)-(pyridin-3-yl)methylideneamino]ethyl}nicotinamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647883/ https://www.ncbi.nlm.nih.gov/pubmed/23723849 http://dx.doi.org/10.1107/S1600536813008544 |
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