4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate

In the cation of the title compound, C(14)H(13)BrN(+)·C(7)H(7)O(3)S(−), the dihedral angle between the benzene and pyridine rings is 8.34 (11)°. The Br atom is disordered over two positions with site occupancies of 0.74 (2) and 0.26 (2). The mol­ecular structure is stabilized by a weak intra­molecul...

Descripción completa

Detalles Bibliográficos
Autores principales: Kumar, M. Krishna, Sudhahar, S., Sornamurthy, B. M., Chakkaravarthi, G., Kumar, R. Mohan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648231/
https://www.ncbi.nlm.nih.gov/pubmed/23723851
http://dx.doi.org/10.1107/S1600536813009227
_version_ 1782268798157455360
author Kumar, M. Krishna
Sudhahar, S.
Sornamurthy, B. M.
Chakkaravarthi, G.
Kumar, R. Mohan
author_facet Kumar, M. Krishna
Sudhahar, S.
Sornamurthy, B. M.
Chakkaravarthi, G.
Kumar, R. Mohan
author_sort Kumar, M. Krishna
collection PubMed
description In the cation of the title compound, C(14)H(13)BrN(+)·C(7)H(7)O(3)S(−), the dihedral angle between the benzene and pyridine rings is 8.34 (11)°. The Br atom is disordered over two positions with site occupancies of 0.74 (2) and 0.26 (2). The mol­ecular structure is stabilized by a weak intra­molecular C—H⋯O inter­actions. The crystal structure exhibits weak C—H⋯O and π–π [centroid–centroid distance = 3.7466 (17) Å] inter­actions, forming a three dimensional network.
format Online
Article
Text
id pubmed-3648231
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36482312013-05-30 4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate Kumar, M. Krishna Sudhahar, S. Sornamurthy, B. M. Chakkaravarthi, G. Kumar, R. Mohan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title compound, C(14)H(13)BrN(+)·C(7)H(7)O(3)S(−), the dihedral angle between the benzene and pyridine rings is 8.34 (11)°. The Br atom is disordered over two positions with site occupancies of 0.74 (2) and 0.26 (2). The mol­ecular structure is stabilized by a weak intra­molecular C—H⋯O inter­actions. The crystal structure exhibits weak C—H⋯O and π–π [centroid–centroid distance = 3.7466 (17) Å] inter­actions, forming a three dimensional network. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3648231/ /pubmed/23723851 http://dx.doi.org/10.1107/S1600536813009227 Text en © Kumar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, M. Krishna
Sudhahar, S.
Sornamurthy, B. M.
Chakkaravarthi, G.
Kumar, R. Mohan
4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate
title 4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate
title_full 4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate
title_fullStr 4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate
title_full_unstemmed 4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate
title_short 4-(4-Bromo­styr­yl)-1-methylpyridinium tosyl­ate
title_sort 4-(4-bromo­styr­yl)-1-methylpyridinium tosyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648231/
https://www.ncbi.nlm.nih.gov/pubmed/23723851
http://dx.doi.org/10.1107/S1600536813009227
work_keys_str_mv AT kumarmkrishna 44bromostyryl1methylpyridiniumtosylate
AT sudhahars 44bromostyryl1methylpyridiniumtosylate
AT sornamurthybm 44bromostyryl1methylpyridiniumtosylate
AT chakkaravarthig 44bromostyryl1methylpyridiniumtosylate
AT kumarrmohan 44bromostyryl1methylpyridiniumtosylate

Ejemplares similares