N-Benzyl­thieno[3,2-d]pyrimidin-4-amine

The title compound, C(13)H(11)N(3)S, crystallizes with two independent mol­ecules in the asymmetric unit. The two mol­ecules are geometrically very similar and differ mainly in a spatial orientation of the benzene and thieno[3,2-d]pyrimidine ring systems [dihedral angles = 69.49 (4) and 79.05 (3)°]....

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Detalles Bibliográficos
Autores principales: Štarha, Pavel, Trávníček, Zdeněk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648234/
https://www.ncbi.nlm.nih.gov/pubmed/23723854
http://dx.doi.org/10.1107/S1600536813009537
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author Štarha, Pavel
Trávníček, Zdeněk
author_facet Štarha, Pavel
Trávníček, Zdeněk
author_sort Štarha, Pavel
collection PubMed
description The title compound, C(13)H(11)N(3)S, crystallizes with two independent mol­ecules in the asymmetric unit. The two mol­ecules are geometrically very similar and differ mainly in a spatial orientation of the benzene and thieno[3,2-d]pyrimidine ring systems [dihedral angles = 69.49 (4) and 79.05 (3)°]. The nine-membered thieno[3,2-d]pyrimidine moieties have a planar conformation (r.m.s. deviations = 0.020 and 0.012 Å). In the crystal, mol­ecules are linked through N—H⋯N, N—H⋯C and C—H⋯π non-covalent contacts into chains along the c axis, while neighbouring chains are connected via C—H⋯N inter­actions.
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spelling pubmed-36482342013-05-30 N-Benzyl­thieno[3,2-d]pyrimidin-4-amine Štarha, Pavel Trávníček, Zdeněk Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(11)N(3)S, crystallizes with two independent mol­ecules in the asymmetric unit. The two mol­ecules are geometrically very similar and differ mainly in a spatial orientation of the benzene and thieno[3,2-d]pyrimidine ring systems [dihedral angles = 69.49 (4) and 79.05 (3)°]. The nine-membered thieno[3,2-d]pyrimidine moieties have a planar conformation (r.m.s. deviations = 0.020 and 0.012 Å). In the crystal, mol­ecules are linked through N—H⋯N, N—H⋯C and C—H⋯π non-covalent contacts into chains along the c axis, while neighbouring chains are connected via C—H⋯N inter­actions. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3648234/ /pubmed/23723854 http://dx.doi.org/10.1107/S1600536813009537 Text en © Štarha and Trávníček 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Štarha, Pavel
Trávníček, Zdeněk
N-Benzyl­thieno[3,2-d]pyrimidin-4-amine
title N-Benzyl­thieno[3,2-d]pyrimidin-4-amine
title_full N-Benzyl­thieno[3,2-d]pyrimidin-4-amine
title_fullStr N-Benzyl­thieno[3,2-d]pyrimidin-4-amine
title_full_unstemmed N-Benzyl­thieno[3,2-d]pyrimidin-4-amine
title_short N-Benzyl­thieno[3,2-d]pyrimidin-4-amine
title_sort n-benzyl­thieno[3,2-d]pyrimidin-4-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648234/
https://www.ncbi.nlm.nih.gov/pubmed/23723854
http://dx.doi.org/10.1107/S1600536813009537
work_keys_str_mv AT starhapavel nbenzylthieno32dpyrimidin4amine
AT travnicekzdenek nbenzylthieno32dpyrimidin4amine

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