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Ethyl 3-(4-chloro­benzo­yl)-1-(4-chloro­benz­yl)-4-(4-chloro­phen­yl)-2,2-dioxo-3,4,6,7,8,8a-hexa­hydro-1H-pyrrolo­[2,1-c][1,4]thia­zine-1-carboxyl­ate

In the title compound, C(30)H(28)Cl(3)NO(5)S, the pyrrolidine ring adopts an envelope conformation (with the N atom as the flap) and the thia­zine ring is in a distorted chair conformation. The mol­ecular structure shows three intra­molecular C—H⋯O inter­actions leading to self-associated ring S(6)...

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Detalles Bibliográficos
Autores principales: Chitradevi, A., Athimoolam, S., Bahadur, S. Asath, Indumathi, S., Perumal, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648240/
https://www.ncbi.nlm.nih.gov/pubmed/23723860
http://dx.doi.org/10.1107/S1600536813009148
Descripción
Sumario:In the title compound, C(30)H(28)Cl(3)NO(5)S, the pyrrolidine ring adopts an envelope conformation (with the N atom as the flap) and the thia­zine ring is in a distorted chair conformation. The mol­ecular structure shows three intra­molecular C—H⋯O inter­actions leading to self-associated ring S(6) and two S(7) motifs. In the crystal, the molecules are linked by C—H⋯O and C—H⋯Cl inter­actions. Two R (2) (2)(10) and one R (2) (2)(16) centrosymmetrically related ring motifs are observed in the unit cell and they are connected through C(6) and C(11) chain motifs extending along the b and c axes, respectively.