1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole

In the title compound, C(29)H(19)F(3)N(2), the tetra­cyclic ring system is essentially planar [maximum deviation from the best plane = 0.076 (1) Å] and makes dihedral angles of 78.10 (5) and 33.71 (4)° with the methyl­phenyl and fluoro­phenyl rings, respectively. An intra­molecular C—H⋯π inter­actio...

Descripción completa

Detalles Bibliográficos
Autores principales: Mohandas, T., Sathishkumar, R., Jayabharathi, J., Pasupathy, A., Sakthivel, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648243/
https://www.ncbi.nlm.nih.gov/pubmed/23723863
http://dx.doi.org/10.1107/S1600536813009471
_version_ 1782268800858587136
author Mohandas, T.
Sathishkumar, R.
Jayabharathi, J.
Pasupathy, A.
Sakthivel, P.
author_facet Mohandas, T.
Sathishkumar, R.
Jayabharathi, J.
Pasupathy, A.
Sakthivel, P.
author_sort Mohandas, T.
collection PubMed
description In the title compound, C(29)H(19)F(3)N(2), the tetra­cyclic ring system is essentially planar [maximum deviation from the best plane = 0.076 (1) Å] and makes dihedral angles of 78.10 (5) and 33.71 (4)° with the methyl­phenyl and fluoro­phenyl rings, respectively. An intra­molecular C—H⋯π inter­action occurs. In the crystal, pairs of C—H⋯π inter­actions link inversion-related mol­ecules.
format Online
Article
Text
id pubmed-3648243
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36482432013-05-30 1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole Mohandas, T. Sathishkumar, R. Jayabharathi, J. Pasupathy, A. Sakthivel, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(19)F(3)N(2), the tetra­cyclic ring system is essentially planar [maximum deviation from the best plane = 0.076 (1) Å] and makes dihedral angles of 78.10 (5) and 33.71 (4)° with the methyl­phenyl and fluoro­phenyl rings, respectively. An intra­molecular C—H⋯π inter­action occurs. In the crystal, pairs of C—H⋯π inter­actions link inversion-related mol­ecules. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3648243/ /pubmed/23723863 http://dx.doi.org/10.1107/S1600536813009471 Text en © Mohandas et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohandas, T.
Sathishkumar, R.
Jayabharathi, J.
Pasupathy, A.
Sakthivel, P.
1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole
title 1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole
title_full 1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole
title_fullStr 1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole
title_full_unstemmed 1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole
title_short 1-(4-Methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1H-phenanthro[9,10-d]imida­zole
title_sort 1-(4-methyl­phen­yl)-2-[4-(trifluoro­methyl)phen­yl]-1h-phenanthro[9,10-d]imida­zole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648243/
https://www.ncbi.nlm.nih.gov/pubmed/23723863
http://dx.doi.org/10.1107/S1600536813009471
work_keys_str_mv AT mohandast 14methylphenyl24trifluoromethylphenyl1hphenanthro910dimidazole
AT sathishkumarr 14methylphenyl24trifluoromethylphenyl1hphenanthro910dimidazole
AT jayabharathij 14methylphenyl24trifluoromethylphenyl1hphenanthro910dimidazole
AT pasupathya 14methylphenyl24trifluoromethylphenyl1hphenanthro910dimidazole
AT sakthivelp 14methylphenyl24trifluoromethylphenyl1hphenanthro910dimidazole

Ejemplares similares