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1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione
In the title compound, C(41)H(31)N(3)O(3), the pyrazole and pyrrolidine rings adopt twisted conformations. The mean plane of the pyrazole ring forms dihedral angles of 9.11 (12) and 39.65 (11)° with the phenyl rings. The O atoms deviate from the mean planes of the chromene and acenaphthylene ring...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648244/ https://www.ncbi.nlm.nih.gov/pubmed/23723864 http://dx.doi.org/10.1107/S1600536813009562 |
| _version_ | 1782268801075642368 |
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| author | Jagadeesan, G. Kathirvelan, D. Haribabu, J. Reddy, B. S. R. Sethusankar, K. |
| author_facet | Jagadeesan, G. Kathirvelan, D. Haribabu, J. Reddy, B. S. R. Sethusankar, K. |
| author_sort | Jagadeesan, G. |
| collection | PubMed |
| description | In the title compound, C(41)H(31)N(3)O(3), the pyrazole and pyrrolidine rings adopt twisted conformations. The mean plane of the pyrazole ring forms dihedral angles of 9.11 (12) and 39.65 (11)° with the phenyl rings. The O atoms deviate from the mean planes of the chromene and acenaphthylene ring systems by 0.194 (15) and 0.079 (15) Å, respectively. In the crystal, molecules are linked via pairs of C—H⋯O interactions,forming inversion dimers with an R (2) (2)(12) ring motif. |
| format | Online Article Text |
| id | pubmed-3648244 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36482442013-05-30 1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione Jagadeesan, G. Kathirvelan, D. Haribabu, J. Reddy, B. S. R. Sethusankar, K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(41)H(31)N(3)O(3), the pyrazole and pyrrolidine rings adopt twisted conformations. The mean plane of the pyrazole ring forms dihedral angles of 9.11 (12) and 39.65 (11)° with the phenyl rings. The O atoms deviate from the mean planes of the chromene and acenaphthylene ring systems by 0.194 (15) and 0.079 (15) Å, respectively. In the crystal, molecules are linked via pairs of C—H⋯O interactions,forming inversion dimers with an R (2) (2)(12) ring motif. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3648244/ /pubmed/23723864 http://dx.doi.org/10.1107/S1600536813009562 Text en © Jagadeesan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Jagadeesan, G. Kathirvelan, D. Haribabu, J. Reddy, B. S. R. Sethusankar, K. 1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione |
| title | 1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione |
| title_full | 1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione |
| title_fullStr | 1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione |
| title_full_unstemmed | 1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione |
| title_short | 1′-(1,3-Diphenyl-1H-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′H-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1H)-dione |
| title_sort | 1′-(1,3-diphenyl-1h-pyrazol-4-yl)-2′,3′,5′,6′,7′,7a’-hexahydro-1′h-dispiro[acenaphthylene-1,3′-pyrrolizine-2′,3′′-chromane]-2,4′′(1h)-dione |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648244/ https://www.ncbi.nlm.nih.gov/pubmed/23723864 http://dx.doi.org/10.1107/S1600536813009562 |
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