Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate

There are two independent mol­ecules in the asymmetric unit of the title mol­ecule, C(8)H(9)N(3)S(2), both of which exhibit an E conformation with the pyridine ring and di­thio­carbazate fragment located on opposite sides of the C=N bond. The pyridine ring and di­thio­carbazate group are approximate...

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Autores principales: Wang, Hui, Hossain, Abul-Monsur-Showkot, Wang, Shi-Chao, Tian, Yu-Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648245/
https://www.ncbi.nlm.nih.gov/pubmed/23723865
http://dx.doi.org/10.1107/S1600536813009409
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author Wang, Hui
Hossain, Abul-Monsur-Showkot
Wang, Shi-Chao
Tian, Yu-Peng
author_facet Wang, Hui
Hossain, Abul-Monsur-Showkot
Wang, Shi-Chao
Tian, Yu-Peng
author_sort Wang, Hui
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title mol­ecule, C(8)H(9)N(3)S(2), both of which exhibit an E conformation with the pyridine ring and di­thio­carbazate fragment located on opposite sides of the C=N bond. The pyridine ring and di­thio­carbazate group are approximately coplanar, with dihedral angles of 4.74 (1) and 8.77 (1)° between their planes in the two mol­ecules. In the crystal, mol­ecules are linked to each other via N—H⋯N hydrogen bonds, forming zigzag chains parallel to [10-1].
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spelling pubmed-36482452013-05-30 Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate Wang, Hui Hossain, Abul-Monsur-Showkot Wang, Shi-Chao Tian, Yu-Peng Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title mol­ecule, C(8)H(9)N(3)S(2), both of which exhibit an E conformation with the pyridine ring and di­thio­carbazate fragment located on opposite sides of the C=N bond. The pyridine ring and di­thio­carbazate group are approximately coplanar, with dihedral angles of 4.74 (1) and 8.77 (1)° between their planes in the two mol­ecules. In the crystal, mol­ecules are linked to each other via N—H⋯N hydrogen bonds, forming zigzag chains parallel to [10-1]. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3648245/ /pubmed/23723865 http://dx.doi.org/10.1107/S1600536813009409 Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Hui
Hossain, Abul-Monsur-Showkot
Wang, Shi-Chao
Tian, Yu-Peng
Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate
title Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate
title_full Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate
title_fullStr Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate
title_full_unstemmed Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate
title_short Methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate
title_sort methyl 3-(pyridin-4-yl­methyl­idene)di­thio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648245/
https://www.ncbi.nlm.nih.gov/pubmed/23723865
http://dx.doi.org/10.1107/S1600536813009409
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AT tianyupeng methyl3pyridin4ylmethylidenedithiocarbazate

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