(3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate

In the title compound, C(17)H(12)Cl(2)N(2)O(2)S(2), the di­thia­cyclo­pentane ring has an envelope conformation with one of the methyl­ene C atoms as the flap. The chloro­phenyl rings make a dihedral angle of 82.63 (7)°. In the crystal, π–π inter­actions between the benzene rings of neighbouring mol...

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Autor principal: Yin, Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648247/
https://www.ncbi.nlm.nih.gov/pubmed/23723867
http://dx.doi.org/10.1107/S1600536813009239
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author Yin, Ling
author_facet Yin, Ling
author_sort Yin, Ling
collection PubMed
description In the title compound, C(17)H(12)Cl(2)N(2)O(2)S(2), the di­thia­cyclo­pentane ring has an envelope conformation with one of the methyl­ene C atoms as the flap. The chloro­phenyl rings make a dihedral angle of 82.63 (7)°. In the crystal, π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.547 (2) Å] link the mol­ecules into inversion dimers. Weak non-classical C—H⋯X (X = O, N, Cl) inter­actions further consolidate the packing, forming a layer structure parallel to (110).
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spelling pubmed-36482472013-05-30 (3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate Yin, Ling Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(12)Cl(2)N(2)O(2)S(2), the di­thia­cyclo­pentane ring has an envelope conformation with one of the methyl­ene C atoms as the flap. The chloro­phenyl rings make a dihedral angle of 82.63 (7)°. In the crystal, π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.547 (2) Å] link the mol­ecules into inversion dimers. Weak non-classical C—H⋯X (X = O, N, Cl) inter­actions further consolidate the packing, forming a layer structure parallel to (110). International Union of Crystallography 2013-04-13 /pmc/articles/PMC3648247/ /pubmed/23723867 http://dx.doi.org/10.1107/S1600536813009239 Text en © Ling Yin 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yin, Ling
(3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate
title (3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate
title_full (3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate
title_fullStr (3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate
title_full_unstemmed (3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate
title_short (3-Chloro­phen­yl)[(E)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate
title_sort (3-chloro­phen­yl)[(e)-2-(1,3-di­thio­lan-2-yl­idene)hydrazinyl­idene]methyl 3-chloro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648247/
https://www.ncbi.nlm.nih.gov/pubmed/23723867
http://dx.doi.org/10.1107/S1600536813009239
work_keys_str_mv AT yinling 3chlorophenyle213dithiolan2ylidenehydrazinylidenemethyl3chlorobenzoate

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