5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione

In the title compound, C(19)H(22)FN(3)OS, the dihedral angle between the inclined oxa­diazole and benzene rings is 52.7 (3)°. In the crystal, helical supra­molecular chains along [100] are sustained by N—H⋯S hydrogen bonds supported by methyl­ene–benzene C—H⋯π inter­actions. The crystal studied was...

Descripción completa

Detalles Bibliográficos
Autores principales: Al-Tamimi, Abdul-Malek S., Alafeefy, Ahmed M., El-Emam, Ali A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648262/
https://www.ncbi.nlm.nih.gov/pubmed/23723882
http://dx.doi.org/10.1107/S1600536813009823
_version_ 1782268805096931328
author Al-Tamimi, Abdul-Malek S.
Alafeefy, Ahmed M.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Al-Tamimi, Abdul-Malek S.
Alafeefy, Ahmed M.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Al-Tamimi, Abdul-Malek S.
collection PubMed
description In the title compound, C(19)H(22)FN(3)OS, the dihedral angle between the inclined oxa­diazole and benzene rings is 52.7 (3)°. In the crystal, helical supra­molecular chains along [100] are sustained by N—H⋯S hydrogen bonds supported by methyl­ene–benzene C—H⋯π inter­actions. The crystal studied was an inversion twin with the fractional contribution of the minor component being 0.33 (14).
format Online
Article
Text
id pubmed-3648262
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36482622013-05-30 5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione Al-Tamimi, Abdul-Malek S. Alafeefy, Ahmed M. El-Emam, Ali A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(22)FN(3)OS, the dihedral angle between the inclined oxa­diazole and benzene rings is 52.7 (3)°. In the crystal, helical supra­molecular chains along [100] are sustained by N—H⋯S hydrogen bonds supported by methyl­ene–benzene C—H⋯π inter­actions. The crystal studied was an inversion twin with the fractional contribution of the minor component being 0.33 (14). International Union of Crystallography 2013-04-13 /pmc/articles/PMC3648262/ /pubmed/23723882 http://dx.doi.org/10.1107/S1600536813009823 Text en © Al-Tamimi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Tamimi, Abdul-Malek S.
Alafeefy, Ahmed M.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione
title 5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione
title_full 5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione
title_fullStr 5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione
title_full_unstemmed 5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione
title_short 5-(Adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione
title_sort 5-(adamantan-1-yl)-3-[(4-fluoro­anilino)meth­yl]-2,3-di­hydro-1,3,4-oxa­diazole-2-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648262/
https://www.ncbi.nlm.nih.gov/pubmed/23723882
http://dx.doi.org/10.1107/S1600536813009823
work_keys_str_mv AT altamimiabdulmaleks 5adamantan1yl34fluoroanilinomethyl23dihydro134oxadiazole2thione
AT alafeefyahmedm 5adamantan1yl34fluoroanilinomethyl23dihydro134oxadiazole2thione
AT elemamalia 5adamantan1yl34fluoroanilinomethyl23dihydro134oxadiazole2thione
AT ngseikweng 5adamantan1yl34fluoroanilinomethyl23dihydro134oxadiazole2thione
AT tiekinkedwardrt 5adamantan1yl34fluoroanilinomethyl23dihydro134oxadiazole2thione

Ejemplares similares