(1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate

In the title chiral sulfinic acid ester, C(18)H(26)O(4)S, the cyclo­hexane ring of the menthyl fragment adopts a chair conformation. The mol­ecular shape is defined by the dihedral angle of 47.87 (8)° between the mean planes of the cyclo­hexane and benzene rings. In the crystal, mol­ecules related b...

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Autores principales: Altamura, Maria, Guidi, Antonio, Jierry, Loic, Paoli, Paola, Rossi, Patrizia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648263/
https://www.ncbi.nlm.nih.gov/pubmed/23723883
http://dx.doi.org/10.1107/S1600536813009112
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author Altamura, Maria
Guidi, Antonio
Jierry, Loic
Paoli, Paola
Rossi, Patrizia
author_facet Altamura, Maria
Guidi, Antonio
Jierry, Loic
Paoli, Paola
Rossi, Patrizia
author_sort Altamura, Maria
collection PubMed
description In the title chiral sulfinic acid ester, C(18)H(26)O(4)S, the cyclo­hexane ring of the menthyl fragment adopts a chair conformation. The mol­ecular shape is defined by the dihedral angle of 47.87 (8)° between the mean planes of the cyclo­hexane and benzene rings. In the crystal, mol­ecules related by the screw axis are connected into chains along [010] by weak C(ar)—H⋯O=S contacts.
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spelling pubmed-36482632013-05-30 (1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate Altamura, Maria Guidi, Antonio Jierry, Loic Paoli, Paola Rossi, Patrizia Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title chiral sulfinic acid ester, C(18)H(26)O(4)S, the cyclo­hexane ring of the menthyl fragment adopts a chair conformation. The mol­ecular shape is defined by the dihedral angle of 47.87 (8)° between the mean planes of the cyclo­hexane and benzene rings. In the crystal, mol­ecules related by the screw axis are connected into chains along [010] by weak C(ar)—H⋯O=S contacts. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3648263/ /pubmed/23723883 http://dx.doi.org/10.1107/S1600536813009112 Text en © Altamura et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Altamura, Maria
Guidi, Antonio
Jierry, Loic
Paoli, Paola
Rossi, Patrizia
(1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate
title (1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate
title_full (1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate
title_fullStr (1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate
title_full_unstemmed (1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate
title_short (1R,2S,5R)-(–)-Menthyl (S)-2-(methoxy­carbonyl)­benzene­sulfinate
title_sort (1r,2s,5r)-(–)-menthyl (s)-2-(methoxy­carbonyl)­benzene­sulfinate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648263/
https://www.ncbi.nlm.nih.gov/pubmed/23723883
http://dx.doi.org/10.1107/S1600536813009112
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AT jierryloic 1r2s5rmenthyls2methoxycarbonylbenzenesulfinate
AT paolipaola 1r2s5rmenthyls2methoxycarbonylbenzenesulfinate
AT rossipatrizia 1r2s5rmenthyls2methoxycarbonylbenzenesulfinate

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