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(1S,3R,8R,9S,11R)-10,10-Dibromo-2,2-dichloro-3,7,7,11-tetramethyltetracyclo[6.5.0.0(1,3).0(9,11)]tridecane
The title compound, C(17)H(24)Br(2)Cl(2), was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The asymmetric unit contains two independent molecules. Each molecule...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648270/ https://www.ncbi.nlm.nih.gov/pubmed/23723890 http://dx.doi.org/10.1107/S1600536813010040 |
Sumario: | The title compound, C(17)H(24)Br(2)Cl(2), was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The asymmetric unit contains two independent molecules. Each molecule is built up from fused six-, seven- and two three-membered rings. In both molecules, the six-membered ring has a half-chair conformation, whereas the seven-membered ring displays a boat conformation. No specific intermolecular interactions are noted in the crystal packing. |
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