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Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate

The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°...

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Detalles Bibliográficos
Autores principales: Bassoude, Ibtissam, Berteina-Raboin, Sabine, Essassi, El Mokhtar, Guillaumet, Gérald, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648271/
https://www.ncbi.nlm.nih.gov/pubmed/23723891
http://dx.doi.org/10.1107/S1600536813009902
Descripción
Sumario:The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°. The fused-ring system and the phenyl ring are nearly coplanar, as indicated by the dihedral angle of 1.27 (10)°. In the crystal, mol­ecules form inversion dimers via pairs of C—H⋯O hydrogen bonds. C—H⋯N inter­actions connect the dimers into a three-dimensional network. In addition, π–π contacts are observed, with centroid–centroid distances of 3.426 (2) Å.