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Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate
The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648271/ https://www.ncbi.nlm.nih.gov/pubmed/23723891 http://dx.doi.org/10.1107/S1600536813009902 |
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author | Bassoude, Ibtissam Berteina-Raboin, Sabine Essassi, El Mokhtar Guillaumet, Gérald El Ammari, Lahcen |
author_facet | Bassoude, Ibtissam Berteina-Raboin, Sabine Essassi, El Mokhtar Guillaumet, Gérald El Ammari, Lahcen |
author_sort | Bassoude, Ibtissam |
collection | PubMed |
description | The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°. The fused-ring system and the phenyl ring are nearly coplanar, as indicated by the dihedral angle of 1.27 (10)°. In the crystal, molecules form inversion dimers via pairs of C—H⋯O hydrogen bonds. C—H⋯N interactions connect the dimers into a three-dimensional network. In addition, π–π contacts are observed, with centroid–centroid distances of 3.426 (2) Å. |
format | Online Article Text |
id | pubmed-3648271 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36482712013-05-30 Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate Bassoude, Ibtissam Berteina-Raboin, Sabine Essassi, El Mokhtar Guillaumet, Gérald El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°. The fused-ring system and the phenyl ring are nearly coplanar, as indicated by the dihedral angle of 1.27 (10)°. In the crystal, molecules form inversion dimers via pairs of C—H⋯O hydrogen bonds. C—H⋯N interactions connect the dimers into a three-dimensional network. In addition, π–π contacts are observed, with centroid–centroid distances of 3.426 (2) Å. International Union of Crystallography 2013-04-17 /pmc/articles/PMC3648271/ /pubmed/23723891 http://dx.doi.org/10.1107/S1600536813009902 Text en © Bassoude et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bassoude, Ibtissam Berteina-Raboin, Sabine Essassi, El Mokhtar Guillaumet, Gérald El Ammari, Lahcen Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate |
title | Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate |
title_full | Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate |
title_fullStr | Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate |
title_full_unstemmed | Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate |
title_short | Ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate |
title_sort | ethyl 7-methyl-2-phenylpyrazolo[1,5-a]pyrimidine-5-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648271/ https://www.ncbi.nlm.nih.gov/pubmed/23723891 http://dx.doi.org/10.1107/S1600536813009902 |
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