Cargando…

Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate

The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°...

Descripción completa

Detalles Bibliográficos
Autores principales: Bassoude, Ibtissam, Berteina-Raboin, Sabine, Essassi, El Mokhtar, Guillaumet, Gérald, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648271/
https://www.ncbi.nlm.nih.gov/pubmed/23723891
http://dx.doi.org/10.1107/S1600536813009902
_version_ 1782268807124877312
author Bassoude, Ibtissam
Berteina-Raboin, Sabine
Essassi, El Mokhtar
Guillaumet, Gérald
El Ammari, Lahcen
author_facet Bassoude, Ibtissam
Berteina-Raboin, Sabine
Essassi, El Mokhtar
Guillaumet, Gérald
El Ammari, Lahcen
author_sort Bassoude, Ibtissam
collection PubMed
description The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°. The fused-ring system and the phenyl ring are nearly coplanar, as indicated by the dihedral angle of 1.27 (10)°. In the crystal, mol­ecules form inversion dimers via pairs of C—H⋯O hydrogen bonds. C—H⋯N inter­actions connect the dimers into a three-dimensional network. In addition, π–π contacts are observed, with centroid–centroid distances of 3.426 (2) Å.
format Online
Article
Text
id pubmed-3648271
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36482712013-05-30 Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate Bassoude, Ibtissam Berteina-Raboin, Sabine Essassi, El Mokhtar Guillaumet, Gérald El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The fused pyrazole and pyrimidine rings in the title compound, C(16)H(15)N(3)O(2), are almost coplanar, being inclined to one another by 1.31 (12)°. The mean plane of this fused ring system is nearly coplanar with the phenyl ring, as indicated by the dihedral angle between their planes of 1.31 (12)°. The fused-ring system and the phenyl ring are nearly coplanar, as indicated by the dihedral angle of 1.27 (10)°. In the crystal, mol­ecules form inversion dimers via pairs of C—H⋯O hydrogen bonds. C—H⋯N inter­actions connect the dimers into a three-dimensional network. In addition, π–π contacts are observed, with centroid–centroid distances of 3.426 (2) Å. International Union of Crystallography 2013-04-17 /pmc/articles/PMC3648271/ /pubmed/23723891 http://dx.doi.org/10.1107/S1600536813009902 Text en © Bassoude et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bassoude, Ibtissam
Berteina-Raboin, Sabine
Essassi, El Mokhtar
Guillaumet, Gérald
El Ammari, Lahcen
Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate
title Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate
title_full Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate
title_fullStr Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate
title_full_unstemmed Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate
title_short Ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate
title_sort ethyl 7-methyl-2-phenyl­pyrazolo­[1,5-a]pyrimidine-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648271/
https://www.ncbi.nlm.nih.gov/pubmed/23723891
http://dx.doi.org/10.1107/S1600536813009902
work_keys_str_mv AT bassoudeibtissam ethyl7methyl2phenylpyrazolo15apyrimidine5carboxylate
AT berteinaraboinsabine ethyl7methyl2phenylpyrazolo15apyrimidine5carboxylate
AT essassielmokhtar ethyl7methyl2phenylpyrazolo15apyrimidine5carboxylate
AT guillaumetgerald ethyl7methyl2phenylpyrazolo15apyrimidine5carboxylate
AT elammarilahcen ethyl7methyl2phenylpyrazolo15apyrimidine5carboxylate