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(E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline
In the title compound, C(22)H(16)F(3)N, the C=N bond of the central imine group adopts an E conformation. The dihedral angles between the 2-(trifluoromethyl)phenyl ring and the benzene rings are 9.34 (1) and 68.8 (1)°. The imine group displays a C—C—N=C torsion angle of 41.6 (3)°. In the crystal,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648283/ https://www.ncbi.nlm.nih.gov/pubmed/23723903 http://dx.doi.org/10.1107/S1600536813010283 |
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author | Yu, Byung-Yong Lee, Ji Eun Cho, Yong Seo Cha, Joo Hwan Lee, Jae Kyun |
author_facet | Yu, Byung-Yong Lee, Ji Eun Cho, Yong Seo Cha, Joo Hwan Lee, Jae Kyun |
author_sort | Yu, Byung-Yong |
collection | PubMed |
description | In the title compound, C(22)H(16)F(3)N, the C=N bond of the central imine group adopts an E conformation. The dihedral angles between the 2-(trifluoromethyl)phenyl ring and the benzene rings are 9.34 (1) and 68.8 (1)°. The imine group displays a C—C—N=C torsion angle of 41.6 (3)°. In the crystal, weak C—H⋯F hydrogen bonds link the molecules into chains parallel to the b-axis direction. |
format | Online Article Text |
id | pubmed-3648283 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36482832013-05-30 (E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline Yu, Byung-Yong Lee, Ji Eun Cho, Yong Seo Cha, Joo Hwan Lee, Jae Kyun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(16)F(3)N, the C=N bond of the central imine group adopts an E conformation. The dihedral angles between the 2-(trifluoromethyl)phenyl ring and the benzene rings are 9.34 (1) and 68.8 (1)°. The imine group displays a C—C—N=C torsion angle of 41.6 (3)°. In the crystal, weak C—H⋯F hydrogen bonds link the molecules into chains parallel to the b-axis direction. International Union of Crystallography 2013-04-20 /pmc/articles/PMC3648283/ /pubmed/23723903 http://dx.doi.org/10.1107/S1600536813010283 Text en © Yu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yu, Byung-Yong Lee, Ji Eun Cho, Yong Seo Cha, Joo Hwan Lee, Jae Kyun (E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline |
title | (E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline |
title_full | (E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline |
title_fullStr | (E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline |
title_full_unstemmed | (E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline |
title_short | (E)-N-(3,3-Diphenylallylidene)-2-(trifluoromethyl)aniline |
title_sort | (e)-n-(3,3-diphenylallylidene)-2-(trifluoromethyl)aniline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648283/ https://www.ncbi.nlm.nih.gov/pubmed/23723903 http://dx.doi.org/10.1107/S1600536813010283 |
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