3-[(1-Bromo­naphthalen-2-yl)meth­oxy]-5,5-di­methyl­cyclo­hex-2-enone

In the title compound, C(19)H(19)BrO(2), the cyclo­hexenone ring adopts an envelope conformation with the C atom bearing the methyl substituents as the flap. In the crystal, weak π–π stacking is observed between parallel aromatic rings of adjacent mol­ecules, the centroid–centroid distance being 3.6...

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Detalles Bibliográficos
Autores principales: Fang, Liang-Liang, Liu, Nan, Zhang, Xin-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648284/
https://www.ncbi.nlm.nih.gov/pubmed/23723904
http://dx.doi.org/10.1107/S160053681301026X
Descripción
Sumario:In the title compound, C(19)H(19)BrO(2), the cyclo­hexenone ring adopts an envelope conformation with the C atom bearing the methyl substituents as the flap. In the crystal, weak π–π stacking is observed between parallel aromatic rings of adjacent mol­ecules, the centroid–centroid distance being 3.694 (6) Å. The entire bromonaphthylmethyl unit is disordered over two orientations, with a site-occupancy ratio of 0.5214 (19):0.4786 (19).

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