2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one

In the title compound, C(18)H(21)NO(3), the bicyclic ring system adopts a twin-chair conformation. The two methyl groups attached to the bicycle are in an equatorial orientation for both rings. One of the furan rings is disordered over two orientations with an occupancy ratio of 0.686 (6):0.314 (6)....

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Detalles Bibliográficos
Autores principales: Venkateswaramoorthi, R., Rizwana Begum, S., Hema, R., Krishnasamy, K., Anitha, A.G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648293/
https://www.ncbi.nlm.nih.gov/pubmed/23723913
http://dx.doi.org/10.1107/S1600536813010180
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author Venkateswaramoorthi, R.
Rizwana Begum, S.
Hema, R.
Krishnasamy, K.
Anitha, A.G.
author_facet Venkateswaramoorthi, R.
Rizwana Begum, S.
Hema, R.
Krishnasamy, K.
Anitha, A.G.
author_sort Venkateswaramoorthi, R.
collection PubMed
description In the title compound, C(18)H(21)NO(3), the bicyclic ring system adopts a twin-chair conformation. The two methyl groups attached to the bicycle are in an equatorial orientation for both rings. One of the furan rings is disordered over two orientations with an occupancy ratio of 0.686 (6):0.314 (6). In the crystal, very long N—H⋯O hydrogen bonds connect the mol­ecules into a chain perpendicular to the ac plane.
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spelling pubmed-36482932013-05-30 2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one Venkateswaramoorthi, R. Rizwana Begum, S. Hema, R. Krishnasamy, K. Anitha, A.G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(21)NO(3), the bicyclic ring system adopts a twin-chair conformation. The two methyl groups attached to the bicycle are in an equatorial orientation for both rings. One of the furan rings is disordered over two orientations with an occupancy ratio of 0.686 (6):0.314 (6). In the crystal, very long N—H⋯O hydrogen bonds connect the mol­ecules into a chain perpendicular to the ac plane. International Union of Crystallography 2013-04-20 /pmc/articles/PMC3648293/ /pubmed/23723913 http://dx.doi.org/10.1107/S1600536813010180 Text en © Venkateswaramoorthi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Venkateswaramoorthi, R.
Rizwana Begum, S.
Hema, R.
Krishnasamy, K.
Anitha, A.G.
2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title 2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full 2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_fullStr 2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full_unstemmed 2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_short 2,4-Bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_sort 2,4-bis(furan-2-yl)-1,5-dimethyl-3-aza­bicyclo­[3.3.1]nonan-9-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648293/
https://www.ncbi.nlm.nih.gov/pubmed/23723913
http://dx.doi.org/10.1107/S1600536813010180
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