Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate

The title ester, C(27)H(30)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit whose geometrical features are similar. In each mol­ecule, the pyrrolidine ring adopts an envelope conformation, with the fused C atom shared with the piperidine ring as the flap, and the piperid...

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Detalles Bibliográficos
Autores principales: Selvanayagam, S., Sridhar, B., Kathiravan, S., Raghunathan, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648300/
https://www.ncbi.nlm.nih.gov/pubmed/23723920
http://dx.doi.org/10.1107/S1600536813010489
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author Selvanayagam, S.
Sridhar, B.
Kathiravan, S.
Raghunathan, R.
author_facet Selvanayagam, S.
Sridhar, B.
Kathiravan, S.
Raghunathan, R.
author_sort Selvanayagam, S.
collection PubMed
description The title ester, C(27)H(30)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit whose geometrical features are similar. In each mol­ecule, the pyrrolidine ring adopts an envelope conformation, with the fused C atom shared with the piperidine ring as the flap, and the piperidine ring adopts a chair conformation. In the crystal, C—H⋯π inter­actions link the inversion-related molecules and form a dimeric arrangement in the unit cell.
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spelling pubmed-36483002013-05-30 Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate Selvanayagam, S. Sridhar, B. Kathiravan, S. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title ester, C(27)H(30)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit whose geometrical features are similar. In each mol­ecule, the pyrrolidine ring adopts an envelope conformation, with the fused C atom shared with the piperidine ring as the flap, and the piperidine ring adopts a chair conformation. In the crystal, C—H⋯π inter­actions link the inversion-related molecules and form a dimeric arrangement in the unit cell. International Union of Crystallography 2013-04-20 /pmc/articles/PMC3648300/ /pubmed/23723920 http://dx.doi.org/10.1107/S1600536813010489 Text en © Selvanayagam et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selvanayagam, S.
Sridhar, B.
Kathiravan, S.
Raghunathan, R.
Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate
title Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate
title_full Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate
title_fullStr Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate
title_full_unstemmed Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate
title_short Methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate
title_sort methyl 9-(4-meth­oxy­phen­yl)-19-methyl-3,12-di­aza­penta­cyclo­[10.7.0.0(2,10).0(3,8).0(13,18)]nona­deca-1(19),13(18),14,16-tetra­ene-10-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648300/
https://www.ncbi.nlm.nih.gov/pubmed/23723920
http://dx.doi.org/10.1107/S1600536813010489
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AT raghunathanr methyl94methoxyphenyl19methyl312diazapentacyclo1070021003801318nonadeca11913181416tetraene10carboxylate

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