12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium

In the title boron–dipyrromethene derivative, C(17)H(16)BF(2)N(3), the benzene ring and the boron–dipyrromethene mean plane form a dihedral angle of 55.82 (8)°. In the crystal, pairs of C—H⋯F inter­actions link the mol­ecules, forming inversion dimers. Further C—H⋯F inter­actions link the dimers int...

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Detalles Bibliográficos
Autor principal: Wang, Zhao-Yun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648305/
https://www.ncbi.nlm.nih.gov/pubmed/23723925
http://dx.doi.org/10.1107/S1600536813010404
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author Wang, Zhao-Yun
author_facet Wang, Zhao-Yun
author_sort Wang, Zhao-Yun
collection PubMed
description In the title boron–dipyrromethene derivative, C(17)H(16)BF(2)N(3), the benzene ring and the boron–dipyrromethene mean plane form a dihedral angle of 55.82 (8)°. In the crystal, pairs of C—H⋯F inter­actions link the mol­ecules, forming inversion dimers. Further C—H⋯F inter­actions link the dimers into a three-dimensional network.
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spelling pubmed-36483052013-05-30 12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium Wang, Zhao-Yun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title boron–dipyrromethene derivative, C(17)H(16)BF(2)N(3), the benzene ring and the boron–dipyrromethene mean plane form a dihedral angle of 55.82 (8)°. In the crystal, pairs of C—H⋯F inter­actions link the mol­ecules, forming inversion dimers. Further C—H⋯F inter­actions link the dimers into a three-dimensional network. International Union of Crystallography 2013-04-24 /pmc/articles/PMC3648305/ /pubmed/23723925 http://dx.doi.org/10.1107/S1600536813010404 Text en © Zhao-Yun Wang 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Zhao-Yun
12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium
title 12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium
title_full 12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium
title_fullStr 12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium
title_full_unstemmed 12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium
title_short 12-Di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium
title_sort 12-di­methyl­amino-2,2-di­fluoro-8-phenyl-1λ(5),3-di­aza-2λ(4)-boratri­cyclo­[7.3.0.0(3,7)]dodeca-1(12),4,6,8,10-pentaen-1-ylium
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648305/
https://www.ncbi.nlm.nih.gov/pubmed/23723925
http://dx.doi.org/10.1107/S1600536813010404
work_keys_str_mv AT wangzhaoyun 12dimethylamino22difluoro8phenyl1l53diaza2l4boratricyclo730037dodeca11246810pentaen1ylium

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