(1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile

The mol­ecule of the title compound, C(11)H(15)NO, contains a cyclo­hexa­none ring, three defined stereocenters and an exocyclic double bond. The crystal structure is the result of a study on the Michael addition reaction of (S)-carvone with sodium cyanide using ionic liquids as the reaction medium...

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Detalles Bibliográficos
Autores principales: Rivadulla, Marcos L., Fall, Alioune, González, María, Matos, Maria J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648320/
https://www.ncbi.nlm.nih.gov/pubmed/23723940
http://dx.doi.org/10.1107/S1600536813011197
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author Rivadulla, Marcos L.
Fall, Alioune
González, María
Matos, Maria J.
author_facet Rivadulla, Marcos L.
Fall, Alioune
González, María
Matos, Maria J.
author_sort Rivadulla, Marcos L.
collection PubMed
description The mol­ecule of the title compound, C(11)H(15)NO, contains a cyclo­hexa­none ring, three defined stereocenters and an exocyclic double bond. The crystal structure is the result of a study on the Michael addition reaction of (S)-carvone with sodium cyanide using ionic liquids as the reaction medium and so the absolute configuration is known from the chemistry. The six-membered ring is in a chair conformation.
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spelling pubmed-36483202013-05-30 (1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile Rivadulla, Marcos L. Fall, Alioune González, María Matos, Maria J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(11)H(15)NO, contains a cyclo­hexa­none ring, three defined stereocenters and an exocyclic double bond. The crystal structure is the result of a study on the Michael addition reaction of (S)-carvone with sodium cyanide using ionic liquids as the reaction medium and so the absolute configuration is known from the chemistry. The six-membered ring is in a chair conformation. International Union of Crystallography 2013-04-27 /pmc/articles/PMC3648320/ /pubmed/23723940 http://dx.doi.org/10.1107/S1600536813011197 Text en © Rivadulla et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rivadulla, Marcos L.
Fall, Alioune
González, María
Matos, Maria J.
(1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile
title (1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile
title_full (1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile
title_fullStr (1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile
title_full_unstemmed (1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile
title_short (1S,2S,5S)-2-Methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile
title_sort (1s,2s,5s)-2-methyl-3-oxo-5-(prop-1-en-2-yl)cyclo­hexane-1-carbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648320/
https://www.ncbi.nlm.nih.gov/pubmed/23723940
http://dx.doi.org/10.1107/S1600536813011197
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