1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one

The asymmetric unit of the title compound, C(21)H(21)Cl(2)NO(2), contains two independent mol­ecules that show similar geometrical features. The piperidine ring adopts a distorted boat conformation. The phenyl rings substituted at the 2- and 6-positions of the piperidine ring are oriented at angles...

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Detalles Bibliográficos
Autores principales: Sugumar, P., Kayalvizhi, R., Nirmala, P., .Ponnuswamy, S, Ponnuswamy, M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648321/
https://www.ncbi.nlm.nih.gov/pubmed/23723941
http://dx.doi.org/10.1107/S1600536813010957
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author Sugumar, P.
Kayalvizhi, R.
Nirmala, P.
.Ponnuswamy, S
Ponnuswamy, M. N.
author_facet Sugumar, P.
Kayalvizhi, R.
Nirmala, P.
.Ponnuswamy, S
Ponnuswamy, M. N.
author_sort Sugumar, P.
collection PubMed
description The asymmetric unit of the title compound, C(21)H(21)Cl(2)NO(2), contains two independent mol­ecules that show similar geometrical features. The piperidine ring adopts a distorted boat conformation. The phenyl rings substituted at the 2- and 6-positions of the piperidine ring are oriented at angles of 65.4 (1) [64.7 (2)°] and 89.2 (1)° [86.3 (2)°] with respect to the least-squares plane of the piperidine ring. In the crystal, adjacent mol­ecules are linked by a network of C—H⋯O inter­actions, forming a C(6) chain along the c-axis direction.
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spelling pubmed-36483212013-05-30 1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one Sugumar, P. Kayalvizhi, R. Nirmala, P. .Ponnuswamy, S Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(21)Cl(2)NO(2), contains two independent mol­ecules that show similar geometrical features. The piperidine ring adopts a distorted boat conformation. The phenyl rings substituted at the 2- and 6-positions of the piperidine ring are oriented at angles of 65.4 (1) [64.7 (2)°] and 89.2 (1)° [86.3 (2)°] with respect to the least-squares plane of the piperidine ring. In the crystal, adjacent mol­ecules are linked by a network of C—H⋯O inter­actions, forming a C(6) chain along the c-axis direction. International Union of Crystallography 2013-04-27 /pmc/articles/PMC3648321/ /pubmed/23723941 http://dx.doi.org/10.1107/S1600536813010957 Text en © Sugumar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sugumar, P.
Kayalvizhi, R.
Nirmala, P.
.Ponnuswamy, S
Ponnuswamy, M. N.
1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one
title 1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one
title_full 1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one
title_fullStr 1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one
title_full_unstemmed 1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one
title_short 1-(2,2-Di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one
title_sort 1-(2,2-di­chloro­acet­yl)-3-ethyl-2,6-di­phenyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648321/
https://www.ncbi.nlm.nih.gov/pubmed/23723941
http://dx.doi.org/10.1107/S1600536813010957
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AT ponnuswamys 122dichloroacetyl3ethyl26diphenylpiperidin4one
AT ponnuswamymn 122dichloroacetyl3ethyl26diphenylpiperidin4one

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