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7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole
In the title molecule, C(20)H(15)N(3), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1082 (15) Å]. The pyrrole ring makes dihedral angles of 3.17 (8)/4.10 (9), 7.20 (9) and 44.62 (9)° with the fused benzene, pyrazole and phenyl rings, respectively. In...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648322/ https://www.ncbi.nlm.nih.gov/pubmed/23723942 http://dx.doi.org/10.1107/S1600536813010994 |
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author | Archana, R. Yamuna, E. Thiruvalluvar, A. Rajendra Prasad, K. J. Butcher, R. J. Gupta, Sushil K. Öztürk Yildirim, Sema |
author_facet | Archana, R. Yamuna, E. Thiruvalluvar, A. Rajendra Prasad, K. J. Butcher, R. J. Gupta, Sushil K. Öztürk Yildirim, Sema |
author_sort | Archana, R. |
collection | PubMed |
description | In the title molecule, C(20)H(15)N(3), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1082 (15) Å]. The pyrrole ring makes dihedral angles of 3.17 (8)/4.10 (9), 7.20 (9) and 44.62 (9)° with the fused benzene, pyrazole and phenyl rings, respectively. In the crystal, molecules are linked via N—H⋯N hydrogen bonds, forming an infinite chain along [010]. Molecules are further linked by nine π–π [centroid–centroid distances vary from 3.6864 (11) to 3.9802 (11) Å] and one C—H⋯π interaction, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-3648322 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36483222013-05-30 7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole Archana, R. Yamuna, E. Thiruvalluvar, A. Rajendra Prasad, K. J. Butcher, R. J. Gupta, Sushil K. Öztürk Yildirim, Sema Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(20)H(15)N(3), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1082 (15) Å]. The pyrrole ring makes dihedral angles of 3.17 (8)/4.10 (9), 7.20 (9) and 44.62 (9)° with the fused benzene, pyrazole and phenyl rings, respectively. In the crystal, molecules are linked via N—H⋯N hydrogen bonds, forming an infinite chain along [010]. Molecules are further linked by nine π–π [centroid–centroid distances vary from 3.6864 (11) to 3.9802 (11) Å] and one C—H⋯π interaction, forming a three-dimensional network. International Union of Crystallography 2013-04-27 /pmc/articles/PMC3648322/ /pubmed/23723942 http://dx.doi.org/10.1107/S1600536813010994 Text en © Archana et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Archana, R. Yamuna, E. Thiruvalluvar, A. Rajendra Prasad, K. J. Butcher, R. J. Gupta, Sushil K. Öztürk Yildirim, Sema 7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole |
title | 7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole |
title_full | 7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole |
title_fullStr | 7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole |
title_full_unstemmed | 7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole |
title_short | 7-Methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole |
title_sort | 7-methyl-1-phenyl-1,10-dihydropyrazolo[3,4-a]carbazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648322/ https://www.ncbi.nlm.nih.gov/pubmed/23723942 http://dx.doi.org/10.1107/S1600536813010994 |
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