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7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole

In the title mol­ecule, C(20)H(15)N(3), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1082 (15) Å]. The pyrrole ring makes dihedral angles of 3.17 (8)/4.10 (9), 7.20 (9) and 44.62 (9)° with the fused benzene, pyrazole and phenyl rings, respectively. In...

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Autores principales: Archana, R., Yamuna, E., Thiruvalluvar, A., Rajendra Prasad, K. J., Butcher, R. J., Gupta, Sushil K., Öztürk Yildirim, Sema
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648322/
https://www.ncbi.nlm.nih.gov/pubmed/23723942
http://dx.doi.org/10.1107/S1600536813010994
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author Archana, R.
Yamuna, E.
Thiruvalluvar, A.
Rajendra Prasad, K. J.
Butcher, R. J.
Gupta, Sushil K.
Öztürk Yildirim, Sema
author_facet Archana, R.
Yamuna, E.
Thiruvalluvar, A.
Rajendra Prasad, K. J.
Butcher, R. J.
Gupta, Sushil K.
Öztürk Yildirim, Sema
author_sort Archana, R.
collection PubMed
description In the title mol­ecule, C(20)H(15)N(3), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1082 (15) Å]. The pyrrole ring makes dihedral angles of 3.17 (8)/4.10 (9), 7.20 (9) and 44.62 (9)° with the fused benzene, pyrazole and phenyl rings, respectively. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming an infinite chain along [010]. Mol­ecules are further linked by nine π–π [centroid–centroid distances vary from 3.6864 (11) to 3.9802 (11) Å] and one C—H⋯π inter­action, forming a three-dimensional network.
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spelling pubmed-36483222013-05-30 7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole Archana, R. Yamuna, E. Thiruvalluvar, A. Rajendra Prasad, K. J. Butcher, R. J. Gupta, Sushil K. Öztürk Yildirim, Sema Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(20)H(15)N(3), the atoms in the carbazole unit deviate from planarity [maximum deviation from mean plane = 0.1082 (15) Å]. The pyrrole ring makes dihedral angles of 3.17 (8)/4.10 (9), 7.20 (9) and 44.62 (9)° with the fused benzene, pyrazole and phenyl rings, respectively. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming an infinite chain along [010]. Mol­ecules are further linked by nine π–π [centroid–centroid distances vary from 3.6864 (11) to 3.9802 (11) Å] and one C—H⋯π inter­action, forming a three-dimensional network. International Union of Crystallography 2013-04-27 /pmc/articles/PMC3648322/ /pubmed/23723942 http://dx.doi.org/10.1107/S1600536813010994 Text en © Archana et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Archana, R.
Yamuna, E.
Thiruvalluvar, A.
Rajendra Prasad, K. J.
Butcher, R. J.
Gupta, Sushil K.
Öztürk Yildirim, Sema
7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole
title 7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole
title_full 7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole
title_fullStr 7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole
title_full_unstemmed 7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole
title_short 7-Methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole
title_sort 7-methyl-1-phenyl-1,10-di­hydro­pyrazolo­[3,4-a]carbazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648322/
https://www.ncbi.nlm.nih.gov/pubmed/23723942
http://dx.doi.org/10.1107/S1600536813010994
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