6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole

The title compound, C(16)H(11)ClN(2)S(2), co-crystallizes with a small amount of the 5-chloro- isomer. The ratio of 6-chloro- to 5-chloro- isomers is 0.969 (2):0.031 (2). One thio­phen-2-yl substitutent displays rotational disorder with 80.6 (4)% of the mol­ecules exhibiting the major orientation. I...

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Detalles Bibliográficos
Autores principales: Geiger, David K., Nellist, Michael R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648326/
https://www.ncbi.nlm.nih.gov/pubmed/23723946
http://dx.doi.org/10.1107/S1600536813011124
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author Geiger, David K.
Nellist, Michael R.
author_facet Geiger, David K.
Nellist, Michael R.
author_sort Geiger, David K.
collection PubMed
description The title compound, C(16)H(11)ClN(2)S(2), co-crystallizes with a small amount of the 5-chloro- isomer. The ratio of 6-chloro- to 5-chloro- isomers is 0.969 (2):0.031 (2). One thio­phen-2-yl substitutent displays rotational disorder with 80.6 (4)% of the mol­ecules exhibiting the major orientation. In the crystal, weak C—H⋯N and C—H⋯S hydrogen-bonding inter­actions result in chains of mol­ecules parallel to [001].
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spelling pubmed-36483262013-05-30 6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole Geiger, David K. Nellist, Michael R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(11)ClN(2)S(2), co-crystallizes with a small amount of the 5-chloro- isomer. The ratio of 6-chloro- to 5-chloro- isomers is 0.969 (2):0.031 (2). One thio­phen-2-yl substitutent displays rotational disorder with 80.6 (4)% of the mol­ecules exhibiting the major orientation. In the crystal, weak C—H⋯N and C—H⋯S hydrogen-bonding inter­actions result in chains of mol­ecules parallel to [001]. International Union of Crystallography 2013-04-30 /pmc/articles/PMC3648326/ /pubmed/23723946 http://dx.doi.org/10.1107/S1600536813011124 Text en © Geiger and Nellist 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Geiger, David K.
Nellist, Michael R.
6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole
title 6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole
title_full 6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole
title_fullStr 6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole
title_full_unstemmed 6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole
title_short 6-Chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1H-benzimidazole
title_sort 6-chloro-2-(thio­phen-2-yl)-1-[(thio­phen-2-yl)meth­yl]-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648326/
https://www.ncbi.nlm.nih.gov/pubmed/23723946
http://dx.doi.org/10.1107/S1600536813011124
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