3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione

In the title compound, C(26)H(22)ClFO(2), the cyclo­propane ring is disordered over two orientations, with site-occupancy factors of 0.64 (2) and 0.36 (2). The major occupancy component of the cyclo­propane ring makes dihedral angles of 47.6 (7), 50.4 (7) and 65.4 (7)° with the fluoro-, chloro- and...

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Autores principales: Srinivasan, Thothadri, Senthilkumar, Govindaraj, Manikandan, Haridoss, Gopalakrishnan, Mannathusamy, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648332/
https://www.ncbi.nlm.nih.gov/pubmed/23723952
http://dx.doi.org/10.1107/S1600536813011276
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author Srinivasan, Thothadri
Senthilkumar, Govindaraj
Manikandan, Haridoss
Gopalakrishnan, Mannathusamy
Velmurugan, Devadasan
author_facet Srinivasan, Thothadri
Senthilkumar, Govindaraj
Manikandan, Haridoss
Gopalakrishnan, Mannathusamy
Velmurugan, Devadasan
author_sort Srinivasan, Thothadri
collection PubMed
description In the title compound, C(26)H(22)ClFO(2), the cyclo­propane ring is disordered over two orientations, with site-occupancy factors of 0.64 (2) and 0.36 (2). The major occupancy component of the cyclo­propane ring makes dihedral angles of 47.6 (7), 50.4 (7) and 65.4 (7)° with the fluoro-, chloro- and unsubstituted benzene rings, respectively [the corresponding values for the minor occupancy component are 47.6 (12), 51.0 (12) and 60.9 (12)°]. An intra­molecular C—H⋯O hydrogen bond occurs. The F and Cl atoms deviate by 0.0508 (12) and 0.0592 (7) Å from the planes of their attached benzene rings. In the crystal, C—H⋯F hydrogen bonds link the mol­ecules into chains along the b-axis direction.
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spelling pubmed-36483322013-05-30 3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione Srinivasan, Thothadri Senthilkumar, Govindaraj Manikandan, Haridoss Gopalakrishnan, Mannathusamy Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(22)ClFO(2), the cyclo­propane ring is disordered over two orientations, with site-occupancy factors of 0.64 (2) and 0.36 (2). The major occupancy component of the cyclo­propane ring makes dihedral angles of 47.6 (7), 50.4 (7) and 65.4 (7)° with the fluoro-, chloro- and unsubstituted benzene rings, respectively [the corresponding values for the minor occupancy component are 47.6 (12), 51.0 (12) and 60.9 (12)°]. An intra­molecular C—H⋯O hydrogen bond occurs. The F and Cl atoms deviate by 0.0508 (12) and 0.0592 (7) Å from the planes of their attached benzene rings. In the crystal, C—H⋯F hydrogen bonds link the mol­ecules into chains along the b-axis direction. International Union of Crystallography 2013-04-30 /pmc/articles/PMC3648332/ /pubmed/23723952 http://dx.doi.org/10.1107/S1600536813011276 Text en © Srinivasan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Srinivasan, Thothadri
Senthilkumar, Govindaraj
Manikandan, Haridoss
Gopalakrishnan, Mannathusamy
Velmurugan, Devadasan
3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione
title 3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione
title_full 3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione
title_fullStr 3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione
title_full_unstemmed 3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione
title_short 3-(4-Chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione
title_sort 3-(4-chloro­phen­yl)-1-cyclo­propyl-2-(2-fluoro­phen­yl)-5-phenyl­pentane-1,5-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3648332/
https://www.ncbi.nlm.nih.gov/pubmed/23723952
http://dx.doi.org/10.1107/S1600536813011276
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