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Redox-Inactive Metals Modulate the Reduction Potential in Heterometallic Manganese-Oxido Clusters
Redox-inactive metals are found in biological and heterogeneous water oxidation catalysts, but their roles in catalysis are currently not well understood. A series of high oxidation state tetranuclear-dioxido clusters comprised of three manganese centers and a redox-inactive metal (M) of various cha...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3654670/ https://www.ncbi.nlm.nih.gov/pubmed/23511417 http://dx.doi.org/10.1038/nchem.1578 |