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Copper(II)-Mediated Synthesis of Indolequinones from Bromoquinones and Enamines

The reaction of enamines and bromoquinones in the presence of copper(II) acetate and potassium carbonate results in a regiospecific synthesis of indolequinones. The reaction is broad in scope and scalable and provides a route to the core structure that is present in several biologically interesting...

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Detalles Bibliográficos
Autores principales: Inman, Martyn, Moody, Christopher J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3659408/
https://www.ncbi.nlm.nih.gov/pubmed/23704833
http://dx.doi.org/10.1002/ejoc.201201597
Descripción
Sumario:The reaction of enamines and bromoquinones in the presence of copper(II) acetate and potassium carbonate results in a regiospecific synthesis of indolequinones. The reaction is broad in scope and scalable and provides a route to the core structure that is present in several biologically interesting natural and synthetic compounds.