Fragmentation of Deprotonated Diacylhydrazine Derivatives in Electrospray Ionization Tandem Mass Spectrometry: Generation of Acid Anions via Intramolecular Rearrangement

The gas-phase fragmentation pathways of deprotonated diacylhydrazine derivatives (R(1)(C = O)-N(t-Bu)NH(C = O)R(2), Compounds 1–6) were investigated by the combination of electrospray ionization tandem mass spectrometry (ESI-MS/MS) and theoretical calculations. Upon collisional activation, the depro...

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Detalles Bibliográficos
Autores principales: Jiang, Kezhi, Zhang, Hu, Wang, Jianmei, Li, Fei, Qian, Mingrong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2013
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3660572/
https://www.ncbi.nlm.nih.gov/pubmed/23704891
http://dx.doi.org/10.1371/journal.pone.0063097

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3660572/
https://www.ncbi.nlm.nih.gov/pubmed/23704891
http://dx.doi.org/10.1371/journal.pone.0063097

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