Reductions of Challenging Organic Substrates by a Nickel Complex of a Noninnocent Crown Carbene Ligand

[Image: see text] The first crown-tetracarbene complex of Ni(II) has been prepared, and its crystal structure determined. The complex can be reduced by Na/Hg, with an uptake of two electrons. The reduced complex reductively cleaves arenesulfonamides, including those derived from secondary aliphatic...

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Detalles Bibliográficos
Autores principales: Findlay, Neil J., Park, Stuart R., Schoenebeck, Franziska, Cahard, Elise, Zhou, Sheng-ze, Berlouis, Leonard E. A., Spicer, Mark D., Tuttle, Tell, Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2010
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662396/
https://www.ncbi.nlm.nih.gov/pubmed/20961105
http://dx.doi.org/10.1021/ja107703n

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