Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation

[Image: see text] This commmunication demonstrates the preparation, isolation, and full characterization of superelectrophilic salts based on amidine dications in organic solvent, as their triflate salts. These dications are highly activated toward regiospecific reaction with hydrogen gas under mild...

Descripción completa

Detalles Bibliográficos
Autores principales: Corr, Michael J., Gibson, Kirsty F., Kennedy, Alan R., Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2009
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662400/
https://www.ncbi.nlm.nih.gov/pubmed/19534467
http://dx.doi.org/10.1021/ja9035847
Descripción
Sumario:[Image: see text] This commmunication demonstrates the preparation, isolation, and full characterization of superelectrophilic salts based on amidine dications in organic solvent, as their triflate salts. These dications are highly activated toward regiospecific reaction with hydrogen gas under mild conditions in the presence of a metal catalyst (Pd/C), mimicking the behavior of the natural substrate, N(5),N(10)-methenyltetrahydromethanopterin, in the iron−sulfur cluster-free [Fe]-hydrogenase.

Ejemplares similares