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New Class of Molecular Conductance Switches Based on the [1,3]-Silyl Migration from Silanes to Silenes
[Image: see text] On the basis of first-principles density functional theory calculations, we propose a new molecular photoswitch which exploits a photochemical [1,3]-silyl(germyl) shift leading from a silane to a silene (a Si=C double bonded compound). The silanes investigated herein act as the OFF...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3670211/ https://www.ncbi.nlm.nih.gov/pubmed/23741530 http://dx.doi.org/10.1021/jp400062y |