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A Solid-Contact Ion Selective Electrode for Copper(II) Using a Succinimide Derivative as Ionophore

All-solid-state sensors with polyvinyl chloride (PVC)-based membranes using off-the-shelf N-hydroxysuccinimide (NHS) and succinimide (Succ) ionophores were prepared using DOP (dioctyl phthalate) and NPOE (ortho-nitrophenyloctyl ether) as plasticizers. Good responses were obtained when NHS was used....

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Detalles Bibliográficos
Autores principales: Tutulea-Anastasiu, Mihaela Dana, Wilson, Deivy, del Valle, Manel, Schreiner, Cristina Mihaela, Cretescu, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3673088/
https://www.ncbi.nlm.nih.gov/pubmed/23549362
http://dx.doi.org/10.3390/s130404367
Descripción
Sumario:All-solid-state sensors with polyvinyl chloride (PVC)-based membranes using off-the-shelf N-hydroxysuccinimide (NHS) and succinimide (Succ) ionophores were prepared using DOP (dioctyl phthalate) and NPOE (ortho-nitrophenyloctyl ether) as plasticizers. Good responses were obtained when NHS was used. The potentiometric response of the proposed electrode is independent of pH over the range 2–6. The electrode shows a fast response time of 0.25 s. The electrode exhibits a Super-Nernstian response, with 37.5 mV/decade, with a potentiometric detection limit of 4.4 μM. The proposed sensor revealed good selectivity towards a group of transition metal ions.