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Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides
A co-catalyst of (PPh(3))AuCl/AgOTf for the intermolecular hydroamination of allenes with sulfonamides is shown. The reaction proceeded smoothly under mild conditions for differently substituted allenes giving N-allylic sulfonamides in good yields with high regioselectivity and E-selectivity.
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678397/ https://www.ncbi.nlm.nih.gov/pubmed/23766819 http://dx.doi.org/10.3762/bjoc.9.117 |
| _version_ | 1782272843469291520 |
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| author | Zhang, Chen Zhang, Shao-Qiao Cai, Hua-Jun Cui, Dong-Mei |
| author_facet | Zhang, Chen Zhang, Shao-Qiao Cai, Hua-Jun Cui, Dong-Mei |
| author_sort | Zhang, Chen |
| collection | PubMed |
| description | A co-catalyst of (PPh(3))AuCl/AgOTf for the intermolecular hydroamination of allenes with sulfonamides is shown. The reaction proceeded smoothly under mild conditions for differently substituted allenes giving N-allylic sulfonamides in good yields with high regioselectivity and E-selectivity. |
| format | Online Article Text |
| id | pubmed-3678397 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36783972013-06-13 Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides Zhang, Chen Zhang, Shao-Qiao Cai, Hua-Jun Cui, Dong-Mei Beilstein J Org Chem Full Research Paper A co-catalyst of (PPh(3))AuCl/AgOTf for the intermolecular hydroamination of allenes with sulfonamides is shown. The reaction proceeded smoothly under mild conditions for differently substituted allenes giving N-allylic sulfonamides in good yields with high regioselectivity and E-selectivity. Beilstein-Institut 2013-05-29 /pmc/articles/PMC3678397/ /pubmed/23766819 http://dx.doi.org/10.3762/bjoc.9.117 Text en Copyright © 2013, Zhang et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Zhang, Chen Zhang, Shao-Qiao Cai, Hua-Jun Cui, Dong-Mei Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides |
| title | Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides |
| title_full | Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides |
| title_fullStr | Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides |
| title_full_unstemmed | Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides |
| title_short | Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides |
| title_sort | gold-catalyzed intermolecular hydroamination of allenes with sulfonamides |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678397/ https://www.ncbi.nlm.nih.gov/pubmed/23766819 http://dx.doi.org/10.3762/bjoc.9.117 |
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