Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals

The recently introduced concept of ionic liquid crystals (ILCs) with complementary ion pairs, consisting of both, mesogenic cation and anion, was extended from guanidinium sulfonates to guanidinium sulfonimides. In this preliminary study, the synthesis and mesomorphic properties of selected derivati...

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Autores principales: Butschies, Martin, Neidhardt, Manuel M, Mansueto, Markus, Laschat, Sabine, Tussetschläger, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678594/
https://www.ncbi.nlm.nih.gov/pubmed/23766823
http://dx.doi.org/10.3762/bjoc.9.121
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author Butschies, Martin
Neidhardt, Manuel M
Mansueto, Markus
Laschat, Sabine
Tussetschläger, Stefan
author_facet Butschies, Martin
Neidhardt, Manuel M
Mansueto, Markus
Laschat, Sabine
Tussetschläger, Stefan
author_sort Butschies, Martin
collection PubMed
description The recently introduced concept of ionic liquid crystals (ILCs) with complementary ion pairs, consisting of both, mesogenic cation and anion, was extended from guanidinium sulfonates to guanidinium sulfonimides. In this preliminary study, the synthesis and mesomorphic properties of selected derivatives were described, which provide the first example of an ILC with the sulfonimide anion directly attached to the mesogenic unit.
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spelling pubmed-36785942013-06-13 Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals Butschies, Martin Neidhardt, Manuel M Mansueto, Markus Laschat, Sabine Tussetschläger, Stefan Beilstein J Org Chem Full Research Paper The recently introduced concept of ionic liquid crystals (ILCs) with complementary ion pairs, consisting of both, mesogenic cation and anion, was extended from guanidinium sulfonates to guanidinium sulfonimides. In this preliminary study, the synthesis and mesomorphic properties of selected derivatives were described, which provide the first example of an ILC with the sulfonimide anion directly attached to the mesogenic unit. Beilstein-Institut 2013-06-05 /pmc/articles/PMC3678594/ /pubmed/23766823 http://dx.doi.org/10.3762/bjoc.9.121 Text en Copyright © 2013, Butschies et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Butschies, Martin
Neidhardt, Manuel M
Mansueto, Markus
Laschat, Sabine
Tussetschläger, Stefan
Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals
title Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals
title_full Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals
title_fullStr Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals
title_full_unstemmed Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals
title_short Synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals
title_sort synthesis of guanidinium–sulfonimide ion pairs: towards novel ionic liquid crystals
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678594/
https://www.ncbi.nlm.nih.gov/pubmed/23766823
http://dx.doi.org/10.3762/bjoc.9.121
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