Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones

A combined experimental and computational study on regioselective gold-catalyzed synthetic routes to 1,3-oxazinan-2-ones (kinetically controlled products) and 1,3-oxazin-2-one derivatives (thermodynamically favored) from easily accessible allenic carbamates has been carried out.

Detalles Bibliográficos
Autores principales: Alcaide, Benito, Almendros, Pedro, Quirós, M Teresa, Fernández, Israel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678844/
https://www.ncbi.nlm.nih.gov/pubmed/23766795
http://dx.doi.org/10.3762/bjoc.9.93
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author Alcaide, Benito
Almendros, Pedro
Quirós, M Teresa
Fernández, Israel
author_facet Alcaide, Benito
Almendros, Pedro
Quirós, M Teresa
Fernández, Israel
author_sort Alcaide, Benito
collection PubMed
description A combined experimental and computational study on regioselective gold-catalyzed synthetic routes to 1,3-oxazinan-2-ones (kinetically controlled products) and 1,3-oxazin-2-one derivatives (thermodynamically favored) from easily accessible allenic carbamates has been carried out.
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spelling pubmed-36788442013-06-13 Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones Alcaide, Benito Almendros, Pedro Quirós, M Teresa Fernández, Israel Beilstein J Org Chem Full Research Paper A combined experimental and computational study on regioselective gold-catalyzed synthetic routes to 1,3-oxazinan-2-ones (kinetically controlled products) and 1,3-oxazin-2-one derivatives (thermodynamically favored) from easily accessible allenic carbamates has been carried out. Beilstein-Institut 2013-04-26 /pmc/articles/PMC3678844/ /pubmed/23766795 http://dx.doi.org/10.3762/bjoc.9.93 Text en Copyright © 2013, Alcaide et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Alcaide, Benito
Almendros, Pedro
Quirós, M Teresa
Fernández, Israel
Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones
title Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones
title_full Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones
title_fullStr Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones
title_full_unstemmed Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones
title_short Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones
title_sort gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678844/
https://www.ncbi.nlm.nih.gov/pubmed/23766795
http://dx.doi.org/10.3762/bjoc.9.93
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