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An aniline dication-like transition state in the Bamberger rearrangement
A Bamberger rearrangement of N-phenylhydroxylamine, Ph–N(OH)H, to p-aminophenol was investigated by DFT calculations for the first time. The nitrenium ion, C(6)H(5)–NH(+), suggested and seemingly established as an intermediate was calculated to be absent owing to the high nucleophilicity of the wate...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678851/ https://www.ncbi.nlm.nih.gov/pubmed/23766821 http://dx.doi.org/10.3762/bjoc.9.119 |