(Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride

In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetra­hedral manner by three thio­urea groups and one thio­cyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intra­molecular N—H⋯S hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Shihabuddeen Syed, A., Rajarajan, K., NizamMohideen, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684862/
https://www.ncbi.nlm.nih.gov/pubmed/23794964
http://dx.doi.org/10.1107/S1600536813011847
Descripción
Sumario:In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetra­hedral manner by three thio­urea groups and one thio­cyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intra­molecular N—H⋯S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N—H⋯N and weak N—H⋯Cl inter­actions, generating a three-dimensional network.

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