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(Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride

In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetra­hedral manner by three thio­urea groups and one thio­cyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intra­molecular N—H⋯S hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Shihabuddeen Syed, A., Rajarajan, K., NizamMohideen, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684862/
https://www.ncbi.nlm.nih.gov/pubmed/23794964
http://dx.doi.org/10.1107/S1600536813011847
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author Shihabuddeen Syed, A.
Rajarajan, K.
NizamMohideen, M.
author_facet Shihabuddeen Syed, A.
Rajarajan, K.
NizamMohideen, M.
author_sort Shihabuddeen Syed, A.
collection PubMed
description In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetra­hedral manner by three thio­urea groups and one thio­cyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intra­molecular N—H⋯S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N—H⋯N and weak N—H⋯Cl inter­actions, generating a three-dimensional network.
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spelling pubmed-36848622013-06-21 (Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride Shihabuddeen Syed, A. Rajarajan, K. NizamMohideen, M. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetra­hedral manner by three thio­urea groups and one thio­cyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intra­molecular N—H⋯S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N—H⋯N and weak N—H⋯Cl inter­actions, generating a three-dimensional network. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684862/ /pubmed/23794964 http://dx.doi.org/10.1107/S1600536813011847 Text en © Shihabuddeen Syed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Shihabuddeen Syed, A.
Rajarajan, K.
NizamMohideen, M.
(Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride
title (Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride
title_full (Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride
title_fullStr (Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride
title_full_unstemmed (Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride
title_short (Thio­cyanato-κS)­tris­(thio­urea-κS)mercury(II) chloride
title_sort (thio­cyanato-κs)­tris­(thio­urea-κs)mercury(ii) chloride
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684862/
https://www.ncbi.nlm.nih.gov/pubmed/23794964
http://dx.doi.org/10.1107/S1600536813011847
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