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(Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride
In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetrahedral manner by three thiourea groups and one thiocyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intramolecular N—H⋯S hydrogen bonds...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684862/ https://www.ncbi.nlm.nih.gov/pubmed/23794964 http://dx.doi.org/10.1107/S1600536813011847 |
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author | Shihabuddeen Syed, A. Rajarajan, K. NizamMohideen, M. |
author_facet | Shihabuddeen Syed, A. Rajarajan, K. NizamMohideen, M. |
author_sort | Shihabuddeen Syed, A. |
collection | PubMed |
description | In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetrahedral manner by three thiourea groups and one thiocyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intramolecular N—H⋯S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N—H⋯N and weak N—H⋯Cl interactions, generating a three-dimensional network. |
format | Online Article Text |
id | pubmed-3684862 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848622013-06-21 (Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride Shihabuddeen Syed, A. Rajarajan, K. NizamMohideen, M. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers In the title salt, [Hg(NCS)(CH(4)N(2)S)(3)]Cl, the Hg(2+) ion is coordinated in a severely distorted tetrahedral manner by three thiourea groups and one thiocyanate anion through their S atoms. The S—Hg—S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intramolecular N—H⋯S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N—H⋯N and weak N—H⋯Cl interactions, generating a three-dimensional network. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684862/ /pubmed/23794964 http://dx.doi.org/10.1107/S1600536813011847 Text en © Shihabuddeen Syed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Shihabuddeen Syed, A. Rajarajan, K. NizamMohideen, M. (Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride |
title | (Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride |
title_full | (Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride |
title_fullStr | (Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride |
title_full_unstemmed | (Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride |
title_short | (Thiocyanato-κS)tris(thiourea-κS)mercury(II) chloride |
title_sort | (thiocyanato-κs)tris(thiourea-κs)mercury(ii) chloride |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684862/ https://www.ncbi.nlm.nih.gov/pubmed/23794964 http://dx.doi.org/10.1107/S1600536813011847 |
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