The low-symmetry lanthanum(III) oxotellurate(IV), La(10)Te(12)O(39)

Single crystals of deca­lanthanum(III) dodeca­oxotellurate(IV), La(10)Te(12)O(39), were obtained by reacting La(2)O(3) and TeO(2) in a CsCl flux. Its crystal structure can be viewed as a three-dimensional network of corner- and edge-sharing LaO(8) polyhedra with Te(IV) atoms filling the inter­stitial sites. The Te(IV) atoms with their 5s (2) electron lone pairs distort the LaO(8) polyhedra through variable Te—O bonds. Among the six unique Te sites, four of them define empty channels extending parallel to the a axis. The formation of these channels is a result of the stereochemically active electron lone pairs on the Te(IV) atoms. The atomic arrangement of the Te—O units can be understood on the basis of the valence shell electron pair repulsion (VSEPR) model. A certain degree of disorder is observed in the crystal structure. As a result, one of the five different La sites is split into two positions with an occupancy ratio of 0.875 (2):0.125 (2). Also, one of the oxygen sites is split into two positions in a 0.559 (13):0.441 (13) ratio, and one O site is half-occupied. Such disorder was observed in all measured La(10)Te(12)O(39) crystals.