2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate

The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromo­pyridin-1-ium cations and distorted tetra­hedral (2-amino-5-bromo­pyridine)­tri­chlorido­zincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bond...

Descripción completa

Detalles Bibliográficos
Autores principales: Fitriani, Hansongnern, Kanidtha, Leesakul, Nararak, Pakawatchai, Chaveng, Saithong, Saowanit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684871/
https://www.ncbi.nlm.nih.gov/pubmed/23794973
http://dx.doi.org/10.1107/S1600536813011884
Descripción
Sumario:The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromo­pyridin-1-ium cations and distorted tetra­hedral (2-amino-5-bromo­pyridine)­tri­chlorido­zincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bonds into layers parallel to (101). Short Br⋯Cl contacts of 3.4239 (11) and 3.4503 (12) Å are observed, as well as π–π stacking inter­actions between the pyridine and pyridinium rings, with alternating centroid-to-centroid distances of 3.653 (2) and 3.845 (2) Å.

Ejemplares similares