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2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate

The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromo­pyridin-1-ium cations and distorted tetra­hedral (2-amino-5-bromo­pyridine)­tri­chlorido­zincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bond...

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Autores principales: Fitriani, Hansongnern, Kanidtha, Leesakul, Nararak, Pakawatchai, Chaveng, Saithong, Saowanit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684871/
https://www.ncbi.nlm.nih.gov/pubmed/23794973
http://dx.doi.org/10.1107/S1600536813011884
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author Fitriani,
Hansongnern, Kanidtha
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
author_facet Fitriani,
Hansongnern, Kanidtha
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
author_sort Fitriani,
collection PubMed
description The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromo­pyridin-1-ium cations and distorted tetra­hedral (2-amino-5-bromo­pyridine)­tri­chlorido­zincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bonds into layers parallel to (101). Short Br⋯Cl contacts of 3.4239 (11) and 3.4503 (12) Å are observed, as well as π–π stacking inter­actions between the pyridine and pyridinium rings, with alternating centroid-to-centroid distances of 3.653 (2) and 3.845 (2) Å.
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spelling pubmed-36848712013-06-21 2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate Fitriani, Hansongnern, Kanidtha Leesakul, Nararak Pakawatchai, Chaveng Saithong, Saowanit Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromo­pyridin-1-ium cations and distorted tetra­hedral (2-amino-5-bromo­pyridine)­tri­chlorido­zincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bonds into layers parallel to (101). Short Br⋯Cl contacts of 3.4239 (11) and 3.4503 (12) Å are observed, as well as π–π stacking inter­actions between the pyridine and pyridinium rings, with alternating centroid-to-centroid distances of 3.653 (2) and 3.845 (2) Å. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684871/ /pubmed/23794973 http://dx.doi.org/10.1107/S1600536813011884 Text en © Fitriani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fitriani,
Hansongnern, Kanidtha
Leesakul, Nararak
Pakawatchai, Chaveng
Saithong, Saowanit
2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate
title 2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate
title_full 2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate
title_fullStr 2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate
title_full_unstemmed 2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate
title_short 2-Amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κN (1))trichloridozincate
title_sort 2-amino-5-bromo­pyridin-1-ium (2-amino-5-bromo­pyridine-κn (1))trichloridozincate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684871/
https://www.ncbi.nlm.nih.gov/pubmed/23794973
http://dx.doi.org/10.1107/S1600536813011884
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