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2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN (1))trichloridozincate
The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromopyridin-1-ium cations and distorted tetrahedral (2-amino-5-bromopyridine)trichloridozincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bond...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684871/ https://www.ncbi.nlm.nih.gov/pubmed/23794973 http://dx.doi.org/10.1107/S1600536813011884 |
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author | Fitriani, Hansongnern, Kanidtha Leesakul, Nararak Pakawatchai, Chaveng Saithong, Saowanit |
author_facet | Fitriani, Hansongnern, Kanidtha Leesakul, Nararak Pakawatchai, Chaveng Saithong, Saowanit |
author_sort | Fitriani, |
collection | PubMed |
description | The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromopyridin-1-ium cations and distorted tetrahedral (2-amino-5-bromopyridine)trichloridozincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bonds into layers parallel to (101). Short Br⋯Cl contacts of 3.4239 (11) and 3.4503 (12) Å are observed, as well as π–π stacking interactions between the pyridine and pyridinium rings, with alternating centroid-to-centroid distances of 3.653 (2) and 3.845 (2) Å. |
format | Online Article Text |
id | pubmed-3684871 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848712013-06-21 2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN (1))trichloridozincate Fitriani, Hansongnern, Kanidtha Leesakul, Nararak Pakawatchai, Chaveng Saithong, Saowanit Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title salt, (C(5)H(6)BrN(2))[ZnCl(3)(C(5)H(5)BrN(2))], consists of discrete 2-amino-5-bromopyridin-1-ium cations and distorted tetrahedral (2-amino-5-bromopyridine)trichloridozincate anions. In the crystal, the complex anions and cations are linked via N—H⋯Cl hydrogen bonds into layers parallel to (101). Short Br⋯Cl contacts of 3.4239 (11) and 3.4503 (12) Å are observed, as well as π–π stacking interactions between the pyridine and pyridinium rings, with alternating centroid-to-centroid distances of 3.653 (2) and 3.845 (2) Å. International Union of Crystallography 2013-05-04 /pmc/articles/PMC3684871/ /pubmed/23794973 http://dx.doi.org/10.1107/S1600536813011884 Text en © Fitriani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fitriani, Hansongnern, Kanidtha Leesakul, Nararak Pakawatchai, Chaveng Saithong, Saowanit 2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN (1))trichloridozincate |
title | 2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN
(1))trichloridozincate |
title_full | 2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN
(1))trichloridozincate |
title_fullStr | 2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN
(1))trichloridozincate |
title_full_unstemmed | 2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN
(1))trichloridozincate |
title_short | 2-Amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κN
(1))trichloridozincate |
title_sort | 2-amino-5-bromopyridin-1-ium (2-amino-5-bromopyridine-κn
(1))trichloridozincate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684871/ https://www.ncbi.nlm.nih.gov/pubmed/23794973 http://dx.doi.org/10.1107/S1600536813011884 |
work_keys_str_mv | AT fitriani 2amino5bromopyridin1ium2amino5bromopyridinekn1trichloridozincate AT hansongnernkanidtha 2amino5bromopyridin1ium2amino5bromopyridinekn1trichloridozincate AT leesakulnararak 2amino5bromopyridin1ium2amino5bromopyridinekn1trichloridozincate AT pakawatchaichaveng 2amino5bromopyridin1ium2amino5bromopyridinekn1trichloridozincate AT saithongsaowanit 2amino5bromopyridin1ium2amino5bromopyridinekn1trichloridozincate |