Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]

In the title compound, {(C(4)H(12)N(2))(2)[Li(2)(P(6)O(18))]·4H(2)O}(n), the phosphate ring anion, located around an inversion center, adopts a chair conformation. Adjacent P(6)O(18) rings are linked via corner-sharing by LiO(4) tetra­hedra, generating anionic porous {[Li(2)(P(6)O(18))](4−)}(n) laye...

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Autores principales: Ameur, Iness, Abid, Sonia, Al-Deyab, Salem S., Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684873/
https://www.ncbi.nlm.nih.gov/pubmed/23794975
http://dx.doi.org/10.1107/S1600536813011756
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author Ameur, Iness
Abid, Sonia
Al-Deyab, Salem S.
Rzaigui, Mohamed
author_facet Ameur, Iness
Abid, Sonia
Al-Deyab, Salem S.
Rzaigui, Mohamed
author_sort Ameur, Iness
collection PubMed
description In the title compound, {(C(4)H(12)N(2))(2)[Li(2)(P(6)O(18))]·4H(2)O}(n), the phosphate ring anion, located around an inversion center, adopts a chair conformation. Adjacent P(6)O(18) rings are linked via corner-sharing by LiO(4) tetra­hedra, generating anionic porous {[Li(2)(P(6)O(18))](4−)}(n) layers parallel to (101). The piperazine-1,4-diium cations occupy the pores and develop hydrogen bonds with the inorganic framework. An extensive network of N—H⋯O and O—H⋯O hydrogen-bonding inter­actions link the components into a three-dimensional network and additional stabilization is provided by weak C—H⋯O hydrogen bonds.
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spelling pubmed-36848732013-06-21 Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate] Ameur, Iness Abid, Sonia Al-Deyab, Salem S. Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(4)H(12)N(2))(2)[Li(2)(P(6)O(18))]·4H(2)O}(n), the phosphate ring anion, located around an inversion center, adopts a chair conformation. Adjacent P(6)O(18) rings are linked via corner-sharing by LiO(4) tetra­hedra, generating anionic porous {[Li(2)(P(6)O(18))](4−)}(n) layers parallel to (101). The piperazine-1,4-diium cations occupy the pores and develop hydrogen bonds with the inorganic framework. An extensive network of N—H⋯O and O—H⋯O hydrogen-bonding inter­actions link the components into a three-dimensional network and additional stabilization is provided by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3684873/ /pubmed/23794975 http://dx.doi.org/10.1107/S1600536813011756 Text en © Ameur et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ameur, Iness
Abid, Sonia
Al-Deyab, Salem S.
Rzaigui, Mohamed
Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]
title Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]
title_full Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]
title_fullStr Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]
title_full_unstemmed Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]
title_short Poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]
title_sort poly[bis­(piperazine-1,4-diium) [(μ(4)-cyclo-hexa­phosphato)dilithium] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684873/
https://www.ncbi.nlm.nih.gov/pubmed/23794975
http://dx.doi.org/10.1107/S1600536813011756
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