Cargando…
Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquanickel(II) dihydrate
In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octahedral environment by two N,O-chelating 3-aminopyrazine-2-carboxylate (APZC) ligands in the equatorial plane and two trans-axial aqua ligan...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684875/ https://www.ncbi.nlm.nih.gov/pubmed/23794977 http://dx.doi.org/10.1107/S1600536813012208 |
Sumario: | In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octahedral environment by two N,O-chelating 3-aminopyrazine-2-carboxylate (APZC) ligands in the equatorial plane and two trans-axial aqua ligands. In the crystal, O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds involving the solvent water molecules, aqua and APZC ligands form layers parallel to (010). These layers are linked further via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds involving the axial aqua ligands, amino groups and the carboxylate groups of the APZC ligands, forming a three-dimensional network. |
---|