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Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate

In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octa­hedral environment by two N,O-chelating 3-amino­pyrazine-2-carboxyl­ate (APZC) ligands in the equatorial plane and two trans-axial aqua ligan...

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Autores principales: Bouchene, Rafika, Khadri, Amina, Bouacida, Sofiane, Berrah, Fadila, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684875/
https://www.ncbi.nlm.nih.gov/pubmed/23794977
http://dx.doi.org/10.1107/S1600536813012208
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author Bouchene, Rafika
Khadri, Amina
Bouacida, Sofiane
Berrah, Fadila
Merazig, Hocine
author_facet Bouchene, Rafika
Khadri, Amina
Bouacida, Sofiane
Berrah, Fadila
Merazig, Hocine
author_sort Bouchene, Rafika
collection PubMed
description In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octa­hedral environment by two N,O-chelating 3-amino­pyrazine-2-carboxyl­ate (APZC) ligands in the equatorial plane and two trans-axial aqua ligands. In the crystal, O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds involving the solvent water mol­ecules, aqua and APZC ligands form layers parallel to (010). These layers are linked further via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds involving the axial aqua ligands, amino groups and the carboxyl­ate groups of the APZC ligands, forming a three-dimensional network.
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spelling pubmed-36848752013-06-21 Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate Bouchene, Rafika Khadri, Amina Bouacida, Sofiane Berrah, Fadila Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octa­hedral environment by two N,O-chelating 3-amino­pyrazine-2-carboxyl­ate (APZC) ligands in the equatorial plane and two trans-axial aqua ligands. In the crystal, O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds involving the solvent water mol­ecules, aqua and APZC ligands form layers parallel to (010). These layers are linked further via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds involving the axial aqua ligands, amino groups and the carboxyl­ate groups of the APZC ligands, forming a three-dimensional network. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3684875/ /pubmed/23794977 http://dx.doi.org/10.1107/S1600536813012208 Text en © Bouchene et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bouchene, Rafika
Khadri, Amina
Bouacida, Sofiane
Berrah, Fadila
Merazig, Hocine
Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate
title Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate
title_full Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate
title_fullStr Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate
title_full_unstemmed Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate
title_short Bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) N (1),O)di­aqua­nickel(II) dihydrate
title_sort bis(3-amino­pyrazine-2-carboxyl­ato-κ(2) n (1),o)di­aqua­nickel(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684875/
https://www.ncbi.nlm.nih.gov/pubmed/23794977
http://dx.doi.org/10.1107/S1600536813012208
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