Cargando…
Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquanickel(II) dihydrate
In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octahedral environment by two N,O-chelating 3-aminopyrazine-2-carboxylate (APZC) ligands in the equatorial plane and two trans-axial aqua ligan...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684875/ https://www.ncbi.nlm.nih.gov/pubmed/23794977 http://dx.doi.org/10.1107/S1600536813012208 |
_version_ | 1782273623951671296 |
---|---|
author | Bouchene, Rafika Khadri, Amina Bouacida, Sofiane Berrah, Fadila Merazig, Hocine |
author_facet | Bouchene, Rafika Khadri, Amina Bouacida, Sofiane Berrah, Fadila Merazig, Hocine |
author_sort | Bouchene, Rafika |
collection | PubMed |
description | In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octahedral environment by two N,O-chelating 3-aminopyrazine-2-carboxylate (APZC) ligands in the equatorial plane and two trans-axial aqua ligands. In the crystal, O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds involving the solvent water molecules, aqua and APZC ligands form layers parallel to (010). These layers are linked further via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds involving the axial aqua ligands, amino groups and the carboxylate groups of the APZC ligands, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-3684875 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848752013-06-21 Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquanickel(II) dihydrate Bouchene, Rafika Khadri, Amina Bouacida, Sofiane Berrah, Fadila Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion lies on an inversion center and is coordinated in an slightly distorted octahedral environment by two N,O-chelating 3-aminopyrazine-2-carboxylate (APZC) ligands in the equatorial plane and two trans-axial aqua ligands. In the crystal, O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds involving the solvent water molecules, aqua and APZC ligands form layers parallel to (010). These layers are linked further via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds involving the axial aqua ligands, amino groups and the carboxylate groups of the APZC ligands, forming a three-dimensional network. International Union of Crystallography 2013-05-11 /pmc/articles/PMC3684875/ /pubmed/23794977 http://dx.doi.org/10.1107/S1600536813012208 Text en © Bouchene et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bouchene, Rafika Khadri, Amina Bouacida, Sofiane Berrah, Fadila Merazig, Hocine Bis(3-aminopyrazine-2-carboxylato-κ(2) N (1),O)diaquanickel(II) dihydrate |
title | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquanickel(II) dihydrate |
title_full | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquanickel(II) dihydrate |
title_fullStr | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquanickel(II) dihydrate |
title_full_unstemmed | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquanickel(II) dihydrate |
title_short | Bis(3-aminopyrazine-2-carboxylato-κ(2)
N
(1),O)diaquanickel(II) dihydrate |
title_sort | bis(3-aminopyrazine-2-carboxylato-κ(2)
n
(1),o)diaquanickel(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684875/ https://www.ncbi.nlm.nih.gov/pubmed/23794977 http://dx.doi.org/10.1107/S1600536813012208 |
work_keys_str_mv | AT bouchenerafika bis3aminopyrazine2carboxylatok2n1odiaquanickeliidihydrate AT khadriamina bis3aminopyrazine2carboxylatok2n1odiaquanickeliidihydrate AT bouacidasofiane bis3aminopyrazine2carboxylatok2n1odiaquanickeliidihydrate AT berrahfadila bis3aminopyrazine2carboxylatok2n1odiaquanickeliidihydrate AT merazighocine bis3aminopyrazine2carboxylatok2n1odiaquanickeliidihydrate |