Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV)

In the title compound, [Sn(CH(3))(3)(C(7)H(7)N(2)O(2)S)(H(2)O)], the Sn(IV) atom has a distorted trigonal–bipyramidal coordination geometry, with one carboxyl­ate O atom of the 2-(4-methyl­pyrimidine-2-sulfan­yl)acetate ligand and the O atom of a water mol­ecule in axial positions, and three methyl...

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Autores principales: Gao, Zhiqing, Zhang, Junhong, Hao, Xuyi, Wang, Daqi, Zhang, Tingting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684878/
https://www.ncbi.nlm.nih.gov/pubmed/23794980
http://dx.doi.org/10.1107/S1600536813012622
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author Gao, Zhiqing
Zhang, Junhong
Hao, Xuyi
Wang, Daqi
Zhang, Tingting
author_facet Gao, Zhiqing
Zhang, Junhong
Hao, Xuyi
Wang, Daqi
Zhang, Tingting
author_sort Gao, Zhiqing
collection PubMed
description In the title compound, [Sn(CH(3))(3)(C(7)H(7)N(2)O(2)S)(H(2)O)], the Sn(IV) atom has a distorted trigonal–bipyramidal coordination geometry, with one carboxyl­ate O atom of the 2-(4-methyl­pyrimidine-2-sulfan­yl)acetate ligand and the O atom of a water mol­ecule in axial positions, and three methyl groups in equatorial positions. In the crystal, mol­ecules are linked via O—H⋯O and O—H⋯N hydrogen bonds, forming double-stranded chains propagating along [010].
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spelling pubmed-36848782013-06-21 Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV) Gao, Zhiqing Zhang, Junhong Hao, Xuyi Wang, Daqi Zhang, Tingting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(CH(3))(3)(C(7)H(7)N(2)O(2)S)(H(2)O)], the Sn(IV) atom has a distorted trigonal–bipyramidal coordination geometry, with one carboxyl­ate O atom of the 2-(4-methyl­pyrimidine-2-sulfan­yl)acetate ligand and the O atom of a water mol­ecule in axial positions, and three methyl groups in equatorial positions. In the crystal, mol­ecules are linked via O—H⋯O and O—H⋯N hydrogen bonds, forming double-stranded chains propagating along [010]. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684878/ /pubmed/23794980 http://dx.doi.org/10.1107/S1600536813012622 Text en © Gao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhiqing
Zhang, Junhong
Hao, Xuyi
Wang, Daqi
Zhang, Tingting
Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV)
title Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV)
title_full Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV)
title_fullStr Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV)
title_full_unstemmed Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV)
title_short Aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κO]tin(IV)
title_sort aqua­trimeth­yl[2-(4-methyl­pyrimidin-2-ylsulfan­yl)acetato-κo]tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684878/
https://www.ncbi.nlm.nih.gov/pubmed/23794980
http://dx.doi.org/10.1107/S1600536813012622
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