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[Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate

In the binuclear title complex, [Cu(2)(ClO(4))(1.5)(NO(3))(1.5)(C(18)H(16)N(6)Se)(H(2)O)(5)]NO(3)·H(2)O, both Cu(II) ions are hexa­coordinated by O and N atoms, thus forming axially elongated CuO(4)N(2) octa­hedra. The equatorial plane of each octa­hedron is formed by one chelating pyrazole–pyridine...

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Autores principales: Seredyuk, Maksym, Pavlenko, Vadim A., Znovjyak, Kateryna O., Gumienna-Kontecka, Elzbieta, Iskenderov, Turganbay S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684879/
https://www.ncbi.nlm.nih.gov/pubmed/23794981
http://dx.doi.org/10.1107/S1600536813012178
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author Seredyuk, Maksym
Pavlenko, Vadim A.
Znovjyak, Kateryna O.
Gumienna-Kontecka, Elzbieta
Iskenderov, Turganbay S.
author_facet Seredyuk, Maksym
Pavlenko, Vadim A.
Znovjyak, Kateryna O.
Gumienna-Kontecka, Elzbieta
Iskenderov, Turganbay S.
author_sort Seredyuk, Maksym
collection PubMed
description In the binuclear title complex, [Cu(2)(ClO(4))(1.5)(NO(3))(1.5)(C(18)H(16)N(6)Se)(H(2)O)(5)]NO(3)·H(2)O, both Cu(II) ions are hexa­coordinated by O and N atoms, thus forming axially elongated CuO(4)N(2) octa­hedra. The equatorial plane of each octa­hedron is formed by one chelating pyrazole–pyridine fragment of the organic ligand and two water mol­ecules. The axial positions in one octa­hedron are occupied by a water mol­ecule and a monodentately coordinated perchlorate anion, while those in the other are occupied by a nitrate anion and a disordered perchlorate/nitrate anion with equal site occupancy. The pyrazole–pyridine units of the organic selenide are trans-oriented to each other with a C—Se—C angle of 96.01 (14)°. In the crystal, uncoordinated nitrate anions and the coordinating water mol­ecules are involved in O—H⋯O and N—H⋯O hydrogen bonds, forming a bridge between the pyrazole group and the coordinating water mol­ecules. Further O—H⋯O hydrogen bonds between the complex mol­ecules and a π–π stacking inter­action with a centroid–centroid distance of 3.834 (4) Å are also observed.
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spelling pubmed-36848792013-06-21 [Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate Seredyuk, Maksym Pavlenko, Vadim A. Znovjyak, Kateryna O. Gumienna-Kontecka, Elzbieta Iskenderov, Turganbay S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title complex, [Cu(2)(ClO(4))(1.5)(NO(3))(1.5)(C(18)H(16)N(6)Se)(H(2)O)(5)]NO(3)·H(2)O, both Cu(II) ions are hexa­coordinated by O and N atoms, thus forming axially elongated CuO(4)N(2) octa­hedra. The equatorial plane of each octa­hedron is formed by one chelating pyrazole–pyridine fragment of the organic ligand and two water mol­ecules. The axial positions in one octa­hedron are occupied by a water mol­ecule and a monodentately coordinated perchlorate anion, while those in the other are occupied by a nitrate anion and a disordered perchlorate/nitrate anion with equal site occupancy. The pyrazole–pyridine units of the organic selenide are trans-oriented to each other with a C—Se—C angle of 96.01 (14)°. In the crystal, uncoordinated nitrate anions and the coordinating water mol­ecules are involved in O—H⋯O and N—H⋯O hydrogen bonds, forming a bridge between the pyrazole group and the coordinating water mol­ecules. Further O—H⋯O hydrogen bonds between the complex mol­ecules and a π–π stacking inter­action with a centroid–centroid distance of 3.834 (4) Å are also observed. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684879/ /pubmed/23794981 http://dx.doi.org/10.1107/S1600536813012178 Text en © Seredyuk et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seredyuk, Maksym
Pavlenko, Vadim A.
Znovjyak, Kateryna O.
Gumienna-Kontecka, Elzbieta
Iskenderov, Turganbay S.
[Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate
title [Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate
title_full [Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate
title_fullStr [Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate
title_full_unstemmed [Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate
title_short [Di­aqua­sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κO)copper(II)] nitrate monohydrate
title_sort [di­aqua­sesqui(nitrato-κo)hemi(perchlorato-κo)copper(ii)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1h-pyrazol-4-yl] selenide}-[tri­aqua­(perchlorato-κo)copper(ii)] nitrate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684879/
https://www.ncbi.nlm.nih.gov/pubmed/23794981
http://dx.doi.org/10.1107/S1600536813012178
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