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[Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate
In the binuclear title complex, [Cu(2)(ClO(4))(1.5)(NO(3))(1.5)(C(18)H(16)N(6)Se)(H(2)O)(5)]NO(3)·H(2)O, both Cu(II) ions are hexacoordinated by O and N atoms, thus forming axially elongated CuO(4)N(2) octahedra. The equatorial plane of each octahedron is formed by one chelating pyrazole–pyridine...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684879/ https://www.ncbi.nlm.nih.gov/pubmed/23794981 http://dx.doi.org/10.1107/S1600536813012178 |
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author | Seredyuk, Maksym Pavlenko, Vadim A. Znovjyak, Kateryna O. Gumienna-Kontecka, Elzbieta Iskenderov, Turganbay S. |
author_facet | Seredyuk, Maksym Pavlenko, Vadim A. Znovjyak, Kateryna O. Gumienna-Kontecka, Elzbieta Iskenderov, Turganbay S. |
author_sort | Seredyuk, Maksym |
collection | PubMed |
description | In the binuclear title complex, [Cu(2)(ClO(4))(1.5)(NO(3))(1.5)(C(18)H(16)N(6)Se)(H(2)O)(5)]NO(3)·H(2)O, both Cu(II) ions are hexacoordinated by O and N atoms, thus forming axially elongated CuO(4)N(2) octahedra. The equatorial plane of each octahedron is formed by one chelating pyrazole–pyridine fragment of the organic ligand and two water molecules. The axial positions in one octahedron are occupied by a water molecule and a monodentately coordinated perchlorate anion, while those in the other are occupied by a nitrate anion and a disordered perchlorate/nitrate anion with equal site occupancy. The pyrazole–pyridine units of the organic selenide are trans-oriented to each other with a C—Se—C angle of 96.01 (14)°. In the crystal, uncoordinated nitrate anions and the coordinating water molecules are involved in O—H⋯O and N—H⋯O hydrogen bonds, forming a bridge between the pyrazole group and the coordinating water molecules. Further O—H⋯O hydrogen bonds between the complex molecules and a π–π stacking interaction with a centroid–centroid distance of 3.834 (4) Å are also observed. |
format | Online Article Text |
id | pubmed-3684879 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848792013-06-21 [Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate Seredyuk, Maksym Pavlenko, Vadim A. Znovjyak, Kateryna O. Gumienna-Kontecka, Elzbieta Iskenderov, Turganbay S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title complex, [Cu(2)(ClO(4))(1.5)(NO(3))(1.5)(C(18)H(16)N(6)Se)(H(2)O)(5)]NO(3)·H(2)O, both Cu(II) ions are hexacoordinated by O and N atoms, thus forming axially elongated CuO(4)N(2) octahedra. The equatorial plane of each octahedron is formed by one chelating pyrazole–pyridine fragment of the organic ligand and two water molecules. The axial positions in one octahedron are occupied by a water molecule and a monodentately coordinated perchlorate anion, while those in the other are occupied by a nitrate anion and a disordered perchlorate/nitrate anion with equal site occupancy. The pyrazole–pyridine units of the organic selenide are trans-oriented to each other with a C—Se—C angle of 96.01 (14)°. In the crystal, uncoordinated nitrate anions and the coordinating water molecules are involved in O—H⋯O and N—H⋯O hydrogen bonds, forming a bridge between the pyrazole group and the coordinating water molecules. Further O—H⋯O hydrogen bonds between the complex molecules and a π–π stacking interaction with a centroid–centroid distance of 3.834 (4) Å are also observed. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684879/ /pubmed/23794981 http://dx.doi.org/10.1107/S1600536813012178 Text en © Seredyuk et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Seredyuk, Maksym Pavlenko, Vadim A. Znovjyak, Kateryna O. Gumienna-Kontecka, Elzbieta Iskenderov, Turganbay S. [Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate |
title | [Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate |
title_full | [Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate |
title_fullStr | [Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate |
title_full_unstemmed | [Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate |
title_short | [Diaquasesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κO)copper(II)] nitrate monohydrate |
title_sort | [diaquasesqui(nitrato-κo)hemi(perchlorato-κo)copper(ii)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1h-pyrazol-4-yl] selenide}-[triaqua(perchlorato-κo)copper(ii)] nitrate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684879/ https://www.ncbi.nlm.nih.gov/pubmed/23794981 http://dx.doi.org/10.1107/S1600536813012178 |
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