(O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV)

In the title compound, [Sn(C(6)H(5))(3)(C(2)H(3)OS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The...

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Autores principales: Javed, Fatima, Ali, Saqib, Shah, Wajid, Tahir, M. Nawaz, Ullah, Hameed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684880/
https://www.ncbi.nlm.nih.gov/pubmed/23794982
http://dx.doi.org/10.1107/S1600536813012300
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author Javed, Fatima
Ali, Saqib
Shah, Wajid
Tahir, M. Nawaz
Ullah, Hameed
author_facet Javed, Fatima
Ali, Saqib
Shah, Wajid
Tahir, M. Nawaz
Ullah, Hameed
author_sort Javed, Fatima
collection PubMed
description In the title compound, [Sn(C(6)H(5))(3)(C(2)H(3)OS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).
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spelling pubmed-36848802013-06-21 (O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV) Javed, Fatima Ali, Saqib Shah, Wajid Tahir, M. Nawaz Ullah, Hameed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(6)H(5))(3)(C(2)H(3)OS(2))], the Sn(IV) atom adopts a distorted SnC(3)S tetra­hedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18). International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684880/ /pubmed/23794982 http://dx.doi.org/10.1107/S1600536813012300 Text en © Javed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Javed, Fatima
Ali, Saqib
Shah, Wajid
Tahir, M. Nawaz
Ullah, Hameed
(O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV)
title (O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV)
title_full (O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV)
title_fullStr (O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV)
title_full_unstemmed (O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV)
title_short (O-Methyl di­thio­carbonato-κS)tri­phenyl­tin(IV)
title_sort (o-methyl di­thio­carbonato-κs)tri­phenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684880/
https://www.ncbi.nlm.nih.gov/pubmed/23794982
http://dx.doi.org/10.1107/S1600536813012300
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