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catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2) N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate]
In the crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(CH(3)OH)(2)]·C(12)H(10)N(2)}(n), the Mn(II) cation is coordinated by two terminal N-bonded selenocyanate anions, two methanol molecules and two 1,2-bis(pyridin-4-yl)ethene (bpe) ligands within a slightly distorted oct...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684882/ https://www.ncbi.nlm.nih.gov/pubmed/23794984 http://dx.doi.org/10.1107/S1600536813012609 |
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author | Wöhlert, Susanne Jess, Inke Näther, Christian |
author_facet | Wöhlert, Susanne Jess, Inke Näther, Christian |
author_sort | Wöhlert, Susanne |
collection | PubMed |
description | In the crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(CH(3)OH)(2)]·C(12)H(10)N(2)}(n), the Mn(II) cation is coordinated by two terminal N-bonded selenocyanate anions, two methanol molecules and two 1,2-bis(pyridin-4-yl)ethene (bpe) ligands within a slightly distorted octahedral geometry. The Mn(II) cations are linked into chains along the c-axis direction by the bpe ligands, which are further connected by intermolecular O—H⋯N hydrogen bonding between the methanol H atoms and additional bpe molecules that are not coordinated to the metal atoms. The Mn(II) cation and both crystallographically independent bpe ligands are located on centers of inversion, whereas the selenocyanate and methanol ligands occupy general positions. |
format | Online Article Text |
id | pubmed-3684882 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848822013-06-21 catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2) N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(CH(3)OH)(2)]·C(12)H(10)N(2)}(n), the Mn(II) cation is coordinated by two terminal N-bonded selenocyanate anions, two methanol molecules and two 1,2-bis(pyridin-4-yl)ethene (bpe) ligands within a slightly distorted octahedral geometry. The Mn(II) cations are linked into chains along the c-axis direction by the bpe ligands, which are further connected by intermolecular O—H⋯N hydrogen bonding between the methanol H atoms and additional bpe molecules that are not coordinated to the metal atoms. The Mn(II) cation and both crystallographically independent bpe ligands are located on centers of inversion, whereas the selenocyanate and methanol ligands occupy general positions. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684882/ /pubmed/23794984 http://dx.doi.org/10.1107/S1600536813012609 Text en © Wöhlert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wöhlert, Susanne Jess, Inke Näther, Christian catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2) N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate] |
title |
catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate] |
title_full |
catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate] |
title_fullStr |
catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate] |
title_full_unstemmed |
catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate] |
title_short |
catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′] 1,2-bis(pyridin-4-yl)ethene monosolvate] |
title_sort | catena-poly[[[bis(methanol-κo)bis(selenocyanato-κn)manganese(ii)]-μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
n:n′] 1,2-bis(pyridin-4-yl)ethene monosolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684882/ https://www.ncbi.nlm.nih.gov/pubmed/23794984 http://dx.doi.org/10.1107/S1600536813012609 |
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