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catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]

In the crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(CH(3)OH)(2)]·C(12)H(10)N(2)}(n), the Mn(II) cation is coordin­ated by two terminal N-bonded seleno­cyanate anions, two methanol mol­ecules and two 1,2-bis­(pyridin-4-yl)eth­ene (bpe) ligands within a slightly distorted oct...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684882/
https://www.ncbi.nlm.nih.gov/pubmed/23794984
http://dx.doi.org/10.1107/S1600536813012609
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author Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(CH(3)OH)(2)]·C(12)H(10)N(2)}(n), the Mn(II) cation is coordin­ated by two terminal N-bonded seleno­cyanate anions, two methanol mol­ecules and two 1,2-bis­(pyridin-4-yl)eth­ene (bpe) ligands within a slightly distorted octahedral geometry. The Mn(II) cations are linked into chains along the c-axis direction by the bpe ligands, which are further connected by inter­molecular O—H⋯N hydrogen bonding between the methanol H atoms and additional bpe mol­ecules that are not coordinated to the metal atoms. The Mn(II) cation and both crystallographically independent bpe ligands are located on centers of inversion, whereas the seleno­cyanate and methanol ligands occupy general positions.
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spelling pubmed-36848822013-06-21 catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(CH(3)OH)(2)]·C(12)H(10)N(2)}(n), the Mn(II) cation is coordin­ated by two terminal N-bonded seleno­cyanate anions, two methanol mol­ecules and two 1,2-bis­(pyridin-4-yl)eth­ene (bpe) ligands within a slightly distorted octahedral geometry. The Mn(II) cations are linked into chains along the c-axis direction by the bpe ligands, which are further connected by inter­molecular O—H⋯N hydrogen bonding between the methanol H atoms and additional bpe mol­ecules that are not coordinated to the metal atoms. The Mn(II) cation and both crystallographically independent bpe ligands are located on centers of inversion, whereas the seleno­cyanate and methanol ligands occupy general positions. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684882/ /pubmed/23794984 http://dx.doi.org/10.1107/S1600536813012609 Text en © Wöhlert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Jess, Inke
Näther, Christian
catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]
title catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]
title_full catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]
title_fullStr catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]
title_full_unstemmed catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]
title_short catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]
title_sort catena-poly[[[bis­(methanol-κo)bis­(seleno­cyanato-κn)manganese(ii)]-μ-1,2-bis­(pyridin-4-yl)eth­ene-κ(2) n:n′] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684882/
https://www.ncbi.nlm.nih.gov/pubmed/23794984
http://dx.doi.org/10.1107/S1600536813012609
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