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[Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)

In the title compound, [Ni(C(8)H(14)N(6)S(2))], the Ni(II) ion is coordinated by N(2)S(2) donor atoms of the tetradentate thio­semicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related mol­ecules are linked via pairs of N—H⋯N and N—H⋯S hydrogen bond...

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Autores principales: Shalamzari, Mohammad Safi, Gurbanov, Atash V., Heidic, Seykens, Kia, Reza, Behrouzi, Shabnam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684884/
https://www.ncbi.nlm.nih.gov/pubmed/23794986
http://dx.doi.org/10.1107/S1600536813012816
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author Shalamzari, Mohammad Safi
Gurbanov, Atash V.
Heidic, Seykens
Kia, Reza
Behrouzi, Shabnam
author_facet Shalamzari, Mohammad Safi
Gurbanov, Atash V.
Heidic, Seykens
Kia, Reza
Behrouzi, Shabnam
author_sort Shalamzari, Mohammad Safi
collection PubMed
description In the title compound, [Ni(C(8)H(14)N(6)S(2))], the Ni(II) ion is coordinated by N(2)S(2) donor atoms of the tetradentate thio­semicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related mol­ecules are linked via pairs of N—H⋯N and N—H⋯S hydrogen bonds, forming R (2) (2)(8) ring motifs. Mol­ecules are further linked by slightly weaker N—H⋯N, N—H⋯S and C—H⋯S hydrogen bonds, forming two-dimensional networks which lie parallel to the bc plane.
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spelling pubmed-36848842013-06-21 [Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II) Shalamzari, Mohammad Safi Gurbanov, Atash V. Heidic, Seykens Kia, Reza Behrouzi, Shabnam Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(14)N(6)S(2))], the Ni(II) ion is coordinated by N(2)S(2) donor atoms of the tetradentate thio­semicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related mol­ecules are linked via pairs of N—H⋯N and N—H⋯S hydrogen bonds, forming R (2) (2)(8) ring motifs. Mol­ecules are further linked by slightly weaker N—H⋯N, N—H⋯S and C—H⋯S hydrogen bonds, forming two-dimensional networks which lie parallel to the bc plane. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684884/ /pubmed/23794986 http://dx.doi.org/10.1107/S1600536813012816 Text en © Shalamzari et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shalamzari, Mohammad Safi
Gurbanov, Atash V.
Heidic, Seykens
Kia, Reza
Behrouzi, Shabnam
[Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)
title [Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)
title_full [Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)
title_fullStr [Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)
title_full_unstemmed [Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)
title_short [Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)
title_sort [hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684884/
https://www.ncbi.nlm.nih.gov/pubmed/23794986
http://dx.doi.org/10.1107/S1600536813012816
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