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[Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II)
In the title compound, [Ni(C(8)H(14)N(6)S(2))], the Ni(II) ion is coordinated by N(2)S(2) donor atoms of the tetradentate thiosemicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related molecules are linked via pairs of N—H⋯N and N—H⋯S hydrogen bond...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684884/ https://www.ncbi.nlm.nih.gov/pubmed/23794986 http://dx.doi.org/10.1107/S1600536813012816 |
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author | Shalamzari, Mohammad Safi Gurbanov, Atash V. Heidic, Seykens Kia, Reza Behrouzi, Shabnam |
author_facet | Shalamzari, Mohammad Safi Gurbanov, Atash V. Heidic, Seykens Kia, Reza Behrouzi, Shabnam |
author_sort | Shalamzari, Mohammad Safi |
collection | PubMed |
description | In the title compound, [Ni(C(8)H(14)N(6)S(2))], the Ni(II) ion is coordinated by N(2)S(2) donor atoms of the tetradentate thiosemicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related molecules are linked via pairs of N—H⋯N and N—H⋯S hydrogen bonds, forming R (2) (2)(8) ring motifs. Molecules are further linked by slightly weaker N—H⋯N, N—H⋯S and C—H⋯S hydrogen bonds, forming two-dimensional networks which lie parallel to the bc plane. |
format | Online Article Text |
id | pubmed-3684884 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36848842013-06-21 [Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II) Shalamzari, Mohammad Safi Gurbanov, Atash V. Heidic, Seykens Kia, Reza Behrouzi, Shabnam Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(14)N(6)S(2))], the Ni(II) ion is coordinated by N(2)S(2) donor atoms of the tetradentate thiosemicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related molecules are linked via pairs of N—H⋯N and N—H⋯S hydrogen bonds, forming R (2) (2)(8) ring motifs. Molecules are further linked by slightly weaker N—H⋯N, N—H⋯S and C—H⋯S hydrogen bonds, forming two-dimensional networks which lie parallel to the bc plane. International Union of Crystallography 2013-05-15 /pmc/articles/PMC3684884/ /pubmed/23794986 http://dx.doi.org/10.1107/S1600536813012816 Text en © Shalamzari et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shalamzari, Mohammad Safi Gurbanov, Atash V. Heidic, Seykens Kia, Reza Behrouzi, Shabnam [Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II) |
title | [Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II) |
title_full | [Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II) |
title_fullStr | [Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II) |
title_full_unstemmed | [Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II) |
title_short | [Hexane-2,5-dione bis(thiosemicarbazonato)]nickel(II) |
title_sort | [hexane-2,5-dione bis(thiosemicarbazonato)]nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3684884/ https://www.ncbi.nlm.nih.gov/pubmed/23794986 http://dx.doi.org/10.1107/S1600536813012816 |
work_keys_str_mv | AT shalamzarimohammadsafi hexane25dionebisthiosemicarbazonatonickelii AT gurbanovatashv hexane25dionebisthiosemicarbazonatonickelii AT heidicseykens hexane25dionebisthiosemicarbazonatonickelii AT kiareza hexane25dionebisthiosemicarbazonatonickelii AT behrouzishabnam hexane25dionebisthiosemicarbazonatonickelii |